Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- For a certain chemical reaction, the equilibrium constant K = 2.7 × 10¹0 at 5.00 °C. Calculate the standard Gibbs free energy of reaction. Round your answer to 2 significant digits. AG° = [] kJ x10 X S ?arrow_forwardFor the reaction CO(g) + Cl₂(g) → COC1₂ (9) ΔΗ° 108 kJ and AS⁰ = – 137 J/K The equilibrium constant for this reaction at 268.0 K is Assume that AH° and ASº are independent of temperature. =arrow_forwardThe reduction of iron(III) oxide (Fe2O3) to pure iron during the first step of steelmaking, 2 FeO3(s) 4Fe(s) + 302(g) is driven by the high-temperature combustion of coke, a purified form of coal: C(s) + O2(g) → CO₂ (g) -> 11 ✓12 Suppose at the temperature of a blast furnace the Gibbs free energies of formation AG, of CO2 and Fe2O3 are -447. kJ/mol and -818. kJ/mol, respectively. Calculate the minimum mass of coke needed to produce 7800. kg of pure iron. Round your answer to 2 significant digits. kg 5arrow_forward
- In vacuum distillation, the surrounding pressure inside a chamber is lowered so the solvent boils at a lower temperature. This is useful when isolating compounds that are temperature-sensitive. To what pressure must a chamber be reduced to distill methanol (ΔvapH = 38.56 kJ/mol, TBP = 351 K) at 25.0°C?arrow_forwardCalculate the change in Gibbs energy for each of the sets of ΔrH∘, ΔrS∘, and T.arrow_forwardConsider the oxidation of a generic metal M into a metal oxide as shown in the reaction. 2 M(s) +20₂(g) → M₂O4(s) For this reaction, AH = -4.961 kJ/mol and AS ixn = 12.12 J/(mol-K) at 298 K. What is the standard change in Gibbs free energy for the reaction in the forward direction? AGixn= What is the equilibrium constant of this reaction at 298 K? Kp = What is the equilibrium pressure of O₂(g) over M(s) at 298 K? MacBook Pro tyne URI + kJ/mol Oarrow_forward
- At 25 °C, the equilibrium partial pressures for the reaction 2 A(g) + 4B(g) = 2C(g) + D(g) were found to be P = 4.62 bar, P = 4.70 bar, Pe=5.81 bar, and Pp = 5.90 bar. What is the standard change in Gibbs free energy of this reaction at 25 C? AG kJ/molarrow_forwardThe standard enthalpies of formation of ions in aqueous solutions are obtained by arbitrarily assigning a value of zero to H* ions; that is, AH H* (aq)]=0. H₂O HC1 (g) →H (aq) + Cl¯ (aq) Note: Reference the Thermodynamic properties of pure substances table for additional information. Part 1 of 2 For the following reaction, calculate AH, for the CI ions. Round your answer to 4 significant digits. Part 2 of 2 □ 0x10 X □ 0.0 kJ ΔΗ% = -14.7 mol S Calculate the enthalpy of neutralization when 1 mole of a strong monoprotic acid (such as HCI) is titrated by 1 mole of a strong base (such as KOH) at 25 °C. Round your answer to 3 significant digits. 010arrow_forward4NH3(g) + 3O2(g) → 2N2(g) + 6H2O(l), ΔH = -1530kJmol-1 (1) H2(g) + 1/2O2(g) → H2O(l), ΔH = -288 kJmol-1 (2) Construct an enthalpy cycle and calculate the enthalpy of formation of ammonia.arrow_forward
- using a calibrated solution calorimeter measured a temperature decrease of 1.10 K when 1.00 g of KNO3 was added to 74.40 g of deionized water in the calorimeter. The specific heat capacity of the solution calorimeter was found to be 4.15 J/gK. Calculate the experimental value of the molar heat of solution of KNO3, ΔHsoln. Was the dissolution of this salt exothermic or endothermic?arrow_forwardElement X has an enthalpy of fusion of 59.2 kJ mol-1 at its melting point (684°C). Calculate ΔSsys for the process,X(l) → X(s)At 1 bar and 684°C. Express your answer in units of J mol-1 K-1 to 3 significant figures.arrow_forward
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