Information: LFSE for octahedral complexes of d7 ions:                                           LFSE  = D(0.4 nt2g  -  0.6 neg)-P   If the energy of Δ for the Ni(III) complex [Ni(9-aneN3)2]3+ is 23,200 cm-1, and the spin pairing energy P is 11,200 cm-1, what is the LFSE (Ligand field stabilization energy) for the complex what would be expected about the structure of the complex:   a)         10,560 cm-1     b)  30,560 cm-1     c)  20160 cm-1   d)   26880 cm-1              9-ane-n3

Chemistry by OpenStax (2015-05-04)
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Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
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Chapter19: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 37E: Draw the Crystal field diagrams for [Fe(NO2)6]4- and [FeF6]3-. State whether each complex is high...
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Information: LFSE for octahedral complexes of d7 ions:

                                          LFSE  = D(0.4 nt2g  -  0.6 neg)-P

 

  1. If the energy of Δ for the Ni(III) complex [Ni(9-aneN3)2]3+ is 23,200 cm-1, and the spin pairing energy P is 11,200 cm-1, what is the LFSE (Ligand field stabilization energy) for the complex what would be expected about the structure of the complex:

 

a)         10,560 cm-1     b)  30,560 cm-1     c)  20160 cm-1   d)   26880 cm-1             

9-ane-n3

 

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