Indicate the products A and B that are obtained in the following reactions: OH CH3 + HOCH2-CH₂OH + TSOH → A 1° NaH/THF A + →> B 2º C6H5-CH2Cl Briefly comment on each reaction.

Draw the structural formula for the major product of the following reactions.

An important step in one synthesis of carboxylic acids is the deprotonation of diethyl malonate and its alkyl-substituted derivative: Base CH;CH2O OCH,CH3 CH;CH,0 OCH2CH3 H2 Diethyl malonate Base CH;CH,0 °C `OCH,CH3 CH;CH,O OCH,CH3 R Alkyl substituted diethyl malonate NaOH can deprotonate diethyl malonate effectively, but NaOC(CH3)3 is typically used to deprotonate the alkyl-substituted derivative. Explain why.

Which compound is the dominant product in the reaction shown below? KMNO4 .COOH (A) H*/H,O (B) COOH .COOH (C) (D) HOOC HOOC Compound B Compound C Compound D Compound A

Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium with their conjugated , -unsaturated isomers. Propose a mechanism for this isomerization.

Arrange these compounds in order of increasing acidity: 2,4-dichlorophenol, phenol, cyclohexanol.

The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?

Bhu Please don't provide handwritten solution Write the mechanism of the reaction show with proper arrow formations. Do not combine in one step

Provide synthetic routes for the preparation of the starting materials of azo dye Alizarine Yellow R starting from benzene O₂N -NEN OH CO₂H

Provide the major products of the given reaction.