In petroleum refining, hydrocracking is the catalytic splitting and addition of H₂ to large hydrocarbon molecules and the resultant production of smaller, more volatile, and more saturated molecules. In the laboratory-scale testing of a new catalyst, the following process is run. Fresh fuel oil is fed to the process at a rate of 100.0 kg/h. It is combined with a recycled oil stream, a fresh H₂ feed, and a recycled H₂ stream to enter a catalytic reactor in which hydrocracking occurs. The product stream from the reactor is fed to a gas separator in which unreacted H₂ gas is split off from the product stream and mixed with the fresh H₂ feed for the reactor. The liquid stream from the gas separator is fed to a fractionator which splits the stream into light and heavy fractions; the heavy fraction is recycled and mixed with the fresh heavy oil. The light fraction is collected as product and tested for suitability as a component of a gasoline-like fuel. The molar ratios of atomic H/C in the feed oil and in the light product are 1.87 and 2.27 respectively, and both are free of other atomic species. The mass ratio of recycled oil to light product is 1.40; the molar ratio of H/C in the recycled oil is 2.00. The mass ratio of H₂ to oil fed to the reactor is 0.0430. Overall Process Draw and label a flow diagram and calculate the following quantities by analyzing the overall system. Mass of light fuel produced: Mass of H₂ fed to the process: i kg/h kg/h
In petroleum refining, hydrocracking is the catalytic splitting and addition of H₂ to large hydrocarbon molecules and the resultant production of smaller, more volatile, and more saturated molecules. In the laboratory-scale testing of a new catalyst, the following process is run. Fresh fuel oil is fed to the process at a rate of 100.0 kg/h. It is combined with a recycled oil stream, a fresh H₂ feed, and a recycled H₂ stream to enter a catalytic reactor in which hydrocracking occurs. The product stream from the reactor is fed to a gas separator in which unreacted H₂ gas is split off from the product stream and mixed with the fresh H₂ feed for the reactor. The liquid stream from the gas separator is fed to a fractionator which splits the stream into light and heavy fractions; the heavy fraction is recycled and mixed with the fresh heavy oil. The light fraction is collected as product and tested for suitability as a component of a gasoline-like fuel. The molar ratios of atomic H/C in the feed oil and in the light product are 1.87 and 2.27 respectively, and both are free of other atomic species. The mass ratio of recycled oil to light product is 1.40; the molar ratio of H/C in the recycled oil is 2.00. The mass ratio of H₂ to oil fed to the reactor is 0.0430. Overall Process Draw and label a flow diagram and calculate the following quantities by analyzing the overall system. Mass of light fuel produced: Mass of H₂ fed to the process: i kg/h kg/h
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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