In a suitable reaction vessel, pieces of graphite are mixed with carbon dioxide gas at 1.00 atm and 1000 K. Which two of the following changes will shift the reaction towards the products? kJ.mol-1 C(s) + CO₂ (g) ← 2 CO(g) (A) increase the volume (B) decrease the temperature (C) decrease partial pressure of CO(g) (D) decrease partial pressure of CO₂(g) ΔΗ = 172

1. Look at the attached reaction. What would you have to do to the reaction in order to increase the magnitude of K?

Nitrogen dioxide is produced by reacting nitric oxide and oxygen: 2NO(g) + 02(g) $2NO2(g) ; AH° = -114 kJ Under which reaction conditions would you expect to have the greatest equilibrium yield of nitric oxide? O high temperature, high pressure O low temperature, high pressure O high temperature, low pressure O low temperature, low pressure

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Indicate the major organic product from the reaction shown. CuLi Br

Ammonia (NH3) decomposes to form nitrogen gas and hydrogen gas with an enthalpy of 89.4kJ/mol. Aclosed container is charged with 6.0 atm ammonia and heated to 25.0°C. At equilibrium the pressure of H2 is3.60atm. a. Write the balanced reaction.

What is AG for the reaction l2(g) → 2 1(g) at 25.0 °C if K = 6.1 x 10-2²? (R = 8.314 J/mol.K)

Consider the following reaction where K, = 9.52×10-2 at 350 K: %3D CH4(g) + CC14(g) 2CH2C1½(g) If the three gases are mixed in a rigid container at 350 K so that the partial pressure of each gas is initially one atm, what will happen? Indicate True (T) or False (F) for each of the following: • 1. A reaction will occur in which CH,Cl2(g) is consumed. v 2. K, will increase. • 3. A reaction will occur in which CH, is consumed. • 4. Q is less than K. v 5. The reaction is at equilibrium. No further reaction will occur.

17. The thermochemical equation for the reaction of F2 and water is as follows. AH = -270 kJ F2(g) + 2 H2O (liq)=HF (aq) + O2 (g) Given a system that is initially at equilibrium, which of the following actions cause the reaction to proceed to the right? a) adding O2(g) b) decreasing the temperature c) adding a catalyst d) decreasing the volume of the reaction chamber e) none of the above

What is the increment G degree for the following reaction from the equilibrium constant at the temperature given? CaCO33(s) → CaO(s) + CO2(g)T = 900°C Kp= 1.04