In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)(NH,);CO(aq) the concentration of NH,NCO was followed as a function of time. It was found that a graph of 1/[NH,NCO] versus time in minutes gave a straight line with a slope of 1.45×10² M-' min1 and a y-intercept of 0.893 M-1. Based on this plot, the reaction O order in NHNCO and the rate constant for the reaction is min-!. zero first second

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In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C
NH,NCO(aq)-
→(NH2)½CO(aq)
the concentration of NH,NCO was followed as a function of time.
It was found that a graph of 1/[NHĻNCO] versus time in minutes gave a straight line with a slope of 1.45×10² M' min and
a y-intercept of 0.893 M-1.
Based on this plot, the reaction
|order in NH,NCO and the rate constant for the reaction is
M-1
min-1.
zero
first
second
Transcribed Image Text:1-arr In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)- →(NH2)½CO(aq) the concentration of NH,NCO was followed as a function of time. It was found that a graph of 1/[NHĻNCO] versus time in minutes gave a straight line with a slope of 1.45×10² M' min and a y-intercept of 0.893 M-1. Based on this plot, the reaction |order in NH,NCO and the rate constant for the reaction is M-1 min-1. zero first second
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