Imagine a solution of two liquids that are so similar that their interactions together are the same as in the individual liquids. Will this solution deviate positively from, deviate negatively from, or ideally follow Raoult's law? It will deviate positively. It will deviate negatively. O It will be an ideal solution.

A solution containing 0.10 mol of naphthalene (nonvolatile) and 0.90 mol of benzene is cooled until some solid benzene freezes out. The solution is then decanted off from the solid and the decanted solution is warmed to 80°C, at which temperature the vapor pressure above the solution is found to be 670 torr. The normal freezing and boiling points of pure benzene are 5.5 °C and 80°C, respectively and the molar enthalpy of fusion of benzene ∆fus?=10.67 kJ/mol Assume the solution is ideal. a) Calculate the temperature to which the solution was cooled originally. b) Calculate the number of moles of benzene that froze out.

Ethanol (C₂H₅OH) has a vapor pressure of 93.0 torr and a density of 0.785 g/mL. Pentane (C₅H₁₂) has a vapor pressure of 435.0 torr and a density of 0.626 g/mL. Calculate the vapor pressure (in torr) of a solution containing 495 mL of ethanol and 255 mL of pentane. Assume this solution behaves ideally.

Ethanol (C₂H₅OH) has a vapor pressure of 93.0 torr and a density of 0.785 g/mL. Pentane (C₅H₁₂) has a vapor pressure of 435.0 torr and a density of 0.626 g/mL. Calculate the vapor pressure (in torr) of a solution containing 495 mL of ethanol and 305 mL of pentane. Assume this solution behaves ideally.

True or False1.) The phase diagram of a pure solvent shows a lower freezing point compared to solutions2.) The process of freezing only lowers the kinetic energy of solute particles in a solution3.) Ionic solutes have higher van't hoff factor compared to non ionic solutes4.) The formation of intermolecular forces of attraction requires complete dissolution

How to apply Raoult's law to real solutions Consider mixing a liquid with a vapor pressure of 100 torr with an equimolar amount of a liquid with a vapor pressure of 200 torr. The resulting solution would be predicted to have a vapor pressure of 150 torr if it behaved ideally. If, however, the interactions between the different components are not similar we can see positive or negative deviations from the calculated vapor pressure. An actual vapor pressure greater than that predicted by Raoult's law is said to be a positive deviation and an actual vapor pressure lower than that predicted by Raoult's law is a negative deviation.