i) Hac ++ McLafferty rearrangement enol molecular ion at m/z = 58 m/z = 140 100 105 Rectangular Snip 77 1-phenylpentan-1-one 50 120 162 20 40 60 80 100 120 140 160 180 200 mlz b.If a mass spectrum of the ester ethyl pentanoate (CH3CH2CH2CH2CO2CH2CH3) is recorded, what is the mass of the radical cation formed by the McLafferty rearrangement? c. Which of the following compounds can undergo a McLafferty rearrangement? Relative abundance
i) Hac ++ McLafferty rearrangement enol molecular ion at m/z = 58 m/z = 140 100 105 Rectangular Snip 77 1-phenylpentan-1-one 50 120 162 20 40 60 80 100 120 140 160 180 200 mlz b.If a mass spectrum of the ester ethyl pentanoate (CH3CH2CH2CH2CO2CH2CH3) is recorded, what is the mass of the radical cation formed by the McLafferty rearrangement? c. Which of the following compounds can undergo a McLafferty rearrangement? Relative abundance
Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.7QAP
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In addition to α cleavage, some
a.Draw the products formed from the McLafferty rearrangement of 1phenylpentan-1-one, and identify the fragment that results in the given mass spectrum.
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