Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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I am having trouble distinguishing between primary, secondary and tertiary amines. I read that tertiary amines don't really show a band. I read that N–H wag (primary and secondary amines only) is from 910-665 cm. Im not sure what a "wag " looks like. I am also having trouble matching which amine seen on the spectrum goes to which molecule bc I dont know how to tell what each molecule is (primary , secondary) when its on a benzene ring. 

. Select a compound that best fits the following IR spectrum.
D
4000
a)
NH₂
Me
3000
b)
NH₂
Me
2000
c)
HAVENUMBERI
NH₂
Me
1500
d)
HN
Me
1000
Me.
Me
"N"
500
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Transcribed Image Text:. Select a compound that best fits the following IR spectrum. D 4000 a) NH₂ Me 3000 b) NH₂ Me 2000 c) HAVENUMBERI NH₂ Me 1500 d) HN Me 1000 Me. Me "N" 500
Expert Solution
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Step 1 IR spectrum of amines

The N-H stretching frequency of amines is observed in the region of 3400-3200 cm-1  in the IR spectrum.

Primary amines gives doublet band and a secondary amine gives a single band in the IR spectrum. 

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