Fundamentals Of Analytical Chemistry
9th Edition
ISBN: 9781285640686
Author: Skoog
Publisher: Cengage
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
thumb_up100%
I am getting stuck with finding the mols, grams and percent of Cr^3+.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution
Trending nowThis is a popular solution!
Step by stepSolved in 2 steps
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A 0.4852g sample of an iron ore was dissolved in acid to the 3+ state, then precipitated as Fe2O3 x H2O. The pp was filtered, washed and calcined to Fe2O3, which gave a weight of 0.2481g. Calculate the Fe % in the sample.arrow_forward2. In a laboratory experiment you react 20.0 mL of 25% by mass C2H&N2 with 8.000 NiCl2.6H20 to obtain the product Ni(NH2CH2CH½NH2j3Cl2 complex. The C2H3N2 solution used in this experiment is 25.0% by mass, with a density (d) of 0.950 g/mL. (MW NICI2.6H2O= 237.69 g/mole, MW C2HgN2=60.10 g/mole, MW tris(ethylenediamine)nickel(II)chloride = 309.89 g/mole) a. Write down the balanced equation of the synthesis. b. Determine the number of moles of each reactant that you use. c. Determine which reactant is the limiting reactant, giving your reasoning. Show all your work to get full credit. (5 points) d. Calculate your percent yield if the dry product weighs 7.000 g.arrow_forward2 MnO4- (aq) + 5 C2O42- (aq) + 16 H+ (aq) « 2Mn2+ (aq) + 10 CO2 (g) + 8 H2O(l) 0.4040 g of the unknown compound (K2Zy(C2O4)z . nH2O) was dissolved in 100.0 mL water to make a solution. It was then heated to 80oC and titrated with a KMnO4 solution as shown below: The molarity of KMnO4 = 0.0.02321 M Volume used = 29.25 mL A.) What is the % Oxalate by mass for the unknown solid titrated?arrow_forward
- To measure the iron content of runoff from a ranch a 25.0 mL sample of run off was acidified with HNO3 and treated with excess KSCN to form a red complex. (KSCN itself is colorless.) The solution was then diluted to 100 mL and put into a variable pathlenght cell. For comparison, a 10.0 mL reference sample of 6.80 x 10-4 M Fe3+ was treated with HNO3 and KSCN and diluted to 50.0 mL. The reference was placed in a cell with a 1.00 cm pathlenght. The runoff had the same absorbance as the reference when the pathlenght of the runoff cell was 2.48 cm. What wa the concentraton of iron in the runoff?arrow_forwardPotentially Useful Information Spectrochemical Series: | < Br < SCN < Cl° < NO3¯< F° < OH° < C2O4²- ~ H2O < NCS < NH3 < en < PPH3 A student synthesizes and isolates the following coordination compound [Ni(H2NCH2CH2NH2)3]Cl2 (molar mass = 309.8966 g/mol) according to the balanced reaction below. In the experiment, the student reacts 2.500 g of nickel (II) chloride hexahydrate (molar mass = 237.6878 g/mol) with 4.000 g of ethylenediamine (molar mass = 60.0992 g/mol). After isolating the product, the student collects 3.200 g of the nickel coordination compound. NICI2•6H2O (aq) + 3H2NCH2CH2NH2 (1) → [Ni(H2NCH2CH2NH2)3]Cl2 (s) + 6H2O (1) What is the limiting reactant in the reaction above? In this reaction, the limiting reactant is... O ethylenediamine O nickel (II) chloride hexahydrate O This reaction is stoichiometric, so there is no limiting reactant.arrow_forwardA Chemist collected a 0.4891-g sample of an ore for Fe determination by a redox titration with K2Cr2O7.The ore was carefully crushed prior to weighing and dissolved in HCl and using a Jones reductor the ironin the sample was brought into the +2 oxidation state. After titration with diphenylamine sulfonic acid,itrequired 36.92 mL of 0.02153 M K2Cr2O7 to reach the end point. Calculate the iron content of the ore as%w/w Fe2O3arrow_forward
- A Chemist collected a 0.4891-g sample of an ore for Fe determination by a redox titration with K2Cr2O7.The ore was carefully crushed prior to weighing and dissolved in HCl and using a Jones reductor the ironin the sample was brought into the +2 oxidation state. After titration with diphenylamine sulfonic acid,itrequired 36.92 mL of 0.02153 M K2Cr2O7 to reach the end point. Show your solution why 77.86% is the iron content of the ore as %w/w Fe2O3.arrow_forwardUse the data provided for stock concentration and mass to calculate the concentrations of each solution. Solution A) A stock solution of 0.0100 M solution of K3[Fe(CN)6] is provided. Calculate the volume of the stock solution needed to prepare 100.0 ml of .00200 M K3[Fe(CN)6]. Deionized water should be used to dilute the solution. Solution B) Calculate the volume of solution A needed to prepare 50.0 ml of .0010 M K3[Fe(CN)6]. Deionized water should be used to dilute this solution.arrow_forwardK2Cr2O7 + 7H2C2O4·2H2O → 2K(Cr(C2O4)2(H2O)2) + 6CO2 + 17H2O Calculate theoretical yield of: K[Cr(C204)2(H20)2] · 2H2O (3 g of oxalic acid dihydrate (H2C2O4·2H2O) )(1 g of potassium dichromate (K2Cr2O7) )(20 mL of 95% ethanol)arrow_forward
- An alloy containing Ni, Fe and Cr was analyzed by a complexation titration using EDTA as titrant. A 0.7176 g sample of the alloy was dissolved in HNO3 and diluted to 250 mL in a flask. A 50.00 mL aliquot of the sample, treated with pyrophosphate to mask Fe and Cr, required 26.14 mL of 0.05831 M EDTA to reach the murexide endpoint. A second 50.00 mL aliquot was treated with hexamethylenetetramine to mask Cr and titration with 0.05831 M EDTA required 35.43 mL to reach the murexide endpoint. Finally, a third 50.00 mL aliquot was treated with 50.00 mL of 0.05831 M EDTA and titrated back to the murexide endpoint with 6.21 mL of 0.06316 M Cu(II). the weight percentages of Ni, Fe and Cr in the alloy.arrow_forwardA 5.07-g petroleum specimen was decomposed by wet ashing and subsequently diluted to 500. mL in a volumetric flask. Cobalt was determined by treating 25.00-mL aliquots of this diluted solution as follows: Reagent Volume in mL Co(II), 3.00 ppm Ligand H2O Absorbance 0.00 20.00 5.00 0.416 5.00 20.00 0.00 0.522 Assume that the /ligand chelate obeys Beer’s law and calculate the percentage of cobalt in the original sample.arrow_forwardb) It was determined that the coordination compound (from above) also contained ammonia, NH3. In order to determine the ammonia content, the student weighed 0.2307 g of the coordination compound and thermally decomposed it to release the ammonia. The ammonia was collected in a flask containing 25.00 mL of 0.3120 M HCI. The solution was then titrated with standardized NaOH solution of 0.2512 M. It took 10.45 ml of the NaOH solution to reach to the endpoint. Determine the % ammonia in the coordination compound.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning