How many moles of electrons are transferred overall? 2.  If E°cell = +1.76 V and Ecell = +1.25 V and [VO²⁺], [VO₂⁺] and [Zn²⁺] are all 1.0 M, what is the pH of the reaction?    4.31    0.69    1.70    3.61    None of the given.

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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Chapter19: Electrochemistry
Section: Chapter Questions
Problem 19.70QP: Calculate the standard cell potential of the following cell at 25C. Sn(s)Sn2+(aq)I2(aq)I(aq)
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1. How many moles of electrons are transferred overall?

2.  If E°cell = +1.76 V and Ecell = +1.25 V and [VO²⁺], [VO₂⁺] and [Zn²⁺] are all 1.0 M, what is the pH of the reaction?

   4.31
   0.69
   1.70
   3.61
   None of the given.
Increasing strength as oxidizing agent
Table of Standard Reduction Potentials
Half-Reaction
F₂(g) + 2e →→→ 2F¯ (aq)
O3(g) + 2H¹ (aq) + 2e¯ → O₂(g) + H₂O
Co³+ (aq) + e → Co (aq)
H₂O₂(aq) + 2H(aq) + 2e
→ 2H₂O
PbO₂ (s) + 4H+ (aq) + SO²(aq)
Ce+ (aq) + e
Ce³+ (aq)
+ 2e¯ →→→ PbSO4(s) + 2H₂O
2+
→Mn²+ (aq) + 4H₂O
MnO4 (aq) + 8H+ (aq) + 5e7
Au³+
(aq) + 3e - Au(s)
Cl₂(g) + 2e →→→ 2Cl¯¯(aq)
3+
Cr₂O² (aq) + 14H*(aq) + 6e¯
2Cr³+ (aq) + 7H₂O
2+
MnO₂ (s) + 4H+ (aq) + 2e7
→→Mn²+
(aq) + 2H₂O
O₂(g) + 4H+ (aq) + 4e¯ →→→ 2H₂O
Br₂() +2e7 →→→→2Br (aq)
NO3(aq) + 4H+ (aq) + 3e¯→→→→→ NO(g) + 2H₂O
2Hg²+ (aq) + 2e
Hg2+ (aq)
Hg2+ (aq) + 2e
→ 2Hg(1)
Ag+ (aq) + e →
Ag(s)
Fe³+ (aq) + e→→→→→ Fe²+ (aq)
O₂(g) + 2H+ (aq) + 2e7 →→→→H₂O₂(aq)
MnO4 (aq) + 2H₂O + 3e7
1₂(s) + 2e
21 (aq)
O₂(g) + 2H₂O + 4e¯
→→→40H(aq)
Cu(s)
Cu²+ (aq) + 2e
AgCl(s) + e
Ag(s) + Cl(aq)
SO (aq) + 4H+ (aq) + 2e¯
Cu²+ (aq) + e
Cu (aq)
Sn4+
(aq) + 2e
2H(aq) + 2e
Pb²+ (aq) + 2e-
Sn²+ (aq) + 2e
Ni²+ (aq) + 2e
Co²+
(aq) + 2e
PbSO4(s) + 2e
Cd²+ (aq) + 2e
Fe²+ (aq) + 2e
Cr³+ (aq) + 3e
Zn²+ (aq) + 2e
2H₂O + 2e
Mn²+ (aq) + 2e
A1³+ (aq) + 3e¯
Be²+ (aq) + 2e
Mg2+ (aq) + 2e
Na (aq) + e
2+
Ca²+ (aq) + 2e
Sr²+ (aq) + 2e
Ba²+ (aq) + 2e
K+ (aq) + e → K(s)
Li (aq) + e →
Li(s)
Sn²+ (aq)
H₂(g)
Pb(s)
Sn(s)
Ni(s)
Co(s)
→ Pb(s) + SO² (aq)
Cd(s)
Fe(s)
Cr(s)
Zn(s)
H₂(g) + 2OH(aq)
→→ Mn(s)
Al(s)
Be(s)
Mg(s)
Na(s)
MnO₂ (s) + 40H(aq)
SO₂(g) + 2H₂O
Ca(s)
Sr(s)
→Ba(s)
E°(V)
+2.87
+2.07
+1.82
+1.77
+1.70
+1.61
+1.51
+1.50
+1.36
+1.33
+1.23
+1.23
+1.07
+0.96
+0.92
+0.85
+0.80
+0.77
+0.68
+0.59
+0.53
+0.40
+0.34
+0.22
+0.20
+0.15
+0.13
0.00
-0.13
-0.14
-0.25
-0.28
-0.31
-0.40
-0.44
-0.74
-0.76
-0.83
-1.18
-1.66
-1.85
-2.37
-2.71
-2.87
-2.89
-2.90
-2.93
-3.05
Increasing strength as reducing agent
Transcribed Image Text:Increasing strength as oxidizing agent Table of Standard Reduction Potentials Half-Reaction F₂(g) + 2e →→→ 2F¯ (aq) O3(g) + 2H¹ (aq) + 2e¯ → O₂(g) + H₂O Co³+ (aq) + e → Co (aq) H₂O₂(aq) + 2H(aq) + 2e → 2H₂O PbO₂ (s) + 4H+ (aq) + SO²(aq) Ce+ (aq) + e Ce³+ (aq) + 2e¯ →→→ PbSO4(s) + 2H₂O 2+ →Mn²+ (aq) + 4H₂O MnO4 (aq) + 8H+ (aq) + 5e7 Au³+ (aq) + 3e - Au(s) Cl₂(g) + 2e →→→ 2Cl¯¯(aq) 3+ Cr₂O² (aq) + 14H*(aq) + 6e¯ 2Cr³+ (aq) + 7H₂O 2+ MnO₂ (s) + 4H+ (aq) + 2e7 →→Mn²+ (aq) + 2H₂O O₂(g) + 4H+ (aq) + 4e¯ →→→ 2H₂O Br₂() +2e7 →→→→2Br (aq) NO3(aq) + 4H+ (aq) + 3e¯→→→→→ NO(g) + 2H₂O 2Hg²+ (aq) + 2e Hg2+ (aq) Hg2+ (aq) + 2e → 2Hg(1) Ag+ (aq) + e → Ag(s) Fe³+ (aq) + e→→→→→ Fe²+ (aq) O₂(g) + 2H+ (aq) + 2e7 →→→→H₂O₂(aq) MnO4 (aq) + 2H₂O + 3e7 1₂(s) + 2e 21 (aq) O₂(g) + 2H₂O + 4e¯ →→→40H(aq) Cu(s) Cu²+ (aq) + 2e AgCl(s) + e Ag(s) + Cl(aq) SO (aq) + 4H+ (aq) + 2e¯ Cu²+ (aq) + e Cu (aq) Sn4+ (aq) + 2e 2H(aq) + 2e Pb²+ (aq) + 2e- Sn²+ (aq) + 2e Ni²+ (aq) + 2e Co²+ (aq) + 2e PbSO4(s) + 2e Cd²+ (aq) + 2e Fe²+ (aq) + 2e Cr³+ (aq) + 3e Zn²+ (aq) + 2e 2H₂O + 2e Mn²+ (aq) + 2e A1³+ (aq) + 3e¯ Be²+ (aq) + 2e Mg2+ (aq) + 2e Na (aq) + e 2+ Ca²+ (aq) + 2e Sr²+ (aq) + 2e Ba²+ (aq) + 2e K+ (aq) + e → K(s) Li (aq) + e → Li(s) Sn²+ (aq) H₂(g) Pb(s) Sn(s) Ni(s) Co(s) → Pb(s) + SO² (aq) Cd(s) Fe(s) Cr(s) Zn(s) H₂(g) + 2OH(aq) →→ Mn(s) Al(s) Be(s) Mg(s) Na(s) MnO₂ (s) + 40H(aq) SO₂(g) + 2H₂O Ca(s) Sr(s) →Ba(s) E°(V) +2.87 +2.07 +1.82 +1.77 +1.70 +1.61 +1.51 +1.50 +1.36 +1.33 +1.23 +1.23 +1.07 +0.96 +0.92 +0.85 +0.80 +0.77 +0.68 +0.59 +0.53 +0.40 +0.34 +0.22 +0.20 +0.15 +0.13 0.00 -0.13 -0.14 -0.25 -0.28 -0.31 -0.40 -0.44 -0.74 -0.76 -0.83 -1.18 -1.66 -1.85 -2.37 -2.71 -2.87 -2.89 -2.90 -2.93 -3.05 Increasing strength as reducing agent
For the cell reaction
2V0₂* (aq)
+ Zn(s) + 4H* (aq) → 2VO²+ (aq) + Zn²+ (aq) + 2H₂O(1)
Transcribed Image Text:For the cell reaction 2V0₂* (aq) + Zn(s) + 4H* (aq) → 2VO²+ (aq) + Zn²+ (aq) + 2H₂O(1)
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