College Physics
11th Edition
ISBN: 9781305952300
Author: Raymond A. Serway, Chris Vuille
Publisher: Cengage Learning
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- For a spherical sodium particle of 25 nm radius crystalizing in a BCC structure having a density of 1.51 g/cm^3, estimate the surface energy of the particle. b. Estimate the surface energy of {100},{110} and {111} surfaces of an FCC lattice with bond strength of 7.97 eV and lattice parameter of 4.2 Å. Also compare the energies.arrow_forwardIt is possible to produce very high magnetic fields over small volumes by special techniques. What would be the resonance frequency of an electron spin in an organic radical in a field of 1.0 kT? How does this frequency compare to typical molecular rotational, vibrational, and electronic energy-level separations?arrow_forwardExplain how the likely outcome of the process would change without the contribution of the pairing effect. Include an energy level sketch in your explanation.arrow_forward
- How do I solve for Problem 12.1? This problem is in a chapter called "Molecules," and it is part of a portion called Systems with two or more Atoms.arrow_forward1. Write down all the possible Burgers vectors of perfect dislocations in an FCC metal. 2. For an a/2[1 dislocation line moving on a (11-1) plane in an FCC crystal, what are the line directions (in Miller indices) if the dislocation is of (i) pure screw and (ii) pure edge character? For an a/2[1 dislocation line moving on a (11-1) plane in an FCC crystal, what are the line directions (in Miller indices) if the dislocation is of (i) pure screw and (ii) pure edge character?arrow_forwardBelow is the LCAO for the sp3 hybrid orbital. What is the value for the c²? (The answer mus be a number, not a fraction) Ya = C($25 +02p₂ +$2p, + $2p:) 2Pxarrow_forward
- P9E.11 (a) For a linear conjugated polyene with each of N carbon atoms contributing an electron in a 2p orbital, the energies E, of the resulting A molecular orbitals are given by: E, =a+2B cos- N+1 k=1, 2,.,N Use this expression to make a reasonable empirical estimate of the resonance integral B for the homologous series consisting of ethene, butadiene, hexatriene, and octatetraene given that t-n ultraviolet absorptions from the HOMO to the LUMO occur at 61 500, 46 080, 39 750, and 32 900 cm", respectively. (b) Calculate the T-electron delocalization energy, Egdo:= E, - n(a+ B), of octatetraene, where E, is the total T-electron binding energy and n is the total number of T-electrons. (c) In the context of this Hückel model, the molecular orbitals are written as linear combinations of the carbon 2p orbitals. The coefficient of the jth atomic orbital in the kth molecular orbital is given by: cN sin j=1,2.N jkn j=1, 2,.,N Evaluate the coefficients of each of the six 2p orbitals in each…arrow_forwardA K* and a CI- ion are separated by 0.52 nm. Find the Coulomb component of the binding energy at that distance. Give your answer in electron-volts. (Please include the appropriate sign.) A positive binding energy would mean the ions are unbound and a negative binding energy means they are bound. Note: For this homework problem, round your answer to 2 decimal places.arrow_forwardQ.1. The metals Cu and Pb have diamagnetic susceptibilities -9.63×10-6 and -1.58x10-5, respectively. Furthermore, Pb is a superconductor with T=7.2 K and Bo=800 G. Compare the magnetic energies of Cu and Pb in an external field of 500 G at 7.5 K and 0.1 K; assume the long-wire geometry with the field parallel to the wire. What is the principal difference in the free energy of the Pb sample at the two temperatures and in the presence of the field?arrow_forward
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