1 The Nature Of Chemistry 2 Chemical Compounds 3 Chemical Reactions 4 Energy And Chemical Reactions 5 Electron Configurations And The Periodic Table 6 Covalent Bonding 7 Molecular Structures 8 Properties Of Gases 9 Liquids, Solids, And Materials 10 Fuels, Organic Chemicals, And Polymers 11 Chemical Kinetics: Rates Of Reactions 12 Chemical Equilibrium 13 The Chemistry Of Solutes And Solutions 14 Acids And Bases 15 Additional Aqueous Equilibria 16 Thermodynamics: Directionality Of Chemical Reactions 17 Electrochemistry And Its Applications 18 Nuclear Chemistry 19 The Chemistry Of The Main-group Elements 20 Chemistry Of Selected Transition Elements And Coordination Compounds Chapter11: Chemical Kinetics: Rates Of Reactions
11.1 Reaction Rate 11.2 Effect Of Concentration On Reaction Rate 11.3 Rate Law And Order Of Reactions 11.4 A Nanoscale View: Elementary Reactions 11.5 Temperature And Reaction Rate: The Arrhenius Equation 11.6 Rate Laws For Elementary Reactions 11.7 Reaction Mechanisms 11.8 Catalysts And Reaction Rate 11.9 Enzymes: Biological Catalysts 11.10 Catalysis In Industry Chapter Questions Section: Chapter Questions
Problem ISP: An excellent way to make highly pure nickel metal for use in specialized steel alloys is to... Problem 1QRT Problem 2QRT Problem 3QRT Problem 4QRT Problem 5QRT Problem 6QRT Problem 7QRT Problem 8QRT Problem 9QRT Problem 10QRT Problem 11QRT Problem 12QRT: Cyclobutane can decompose to form ethylene:
The cyclobutane concentration can be measured as a... Problem 13QRT Problem 14QRT Problem 15QRT: For the reaction 2NO2(g)2NO(g)+O2(g) make qualitatively correct plots of the concentrations of... Problem 16QRT Problem 17QRT Problem 18QRT: Ammonia is produced by the reaction between nitrogen and hydrogen gases. (a) Write a balanced... Problem 19QRT Problem 20QRT Problem 21QRT: The reaction of CO(g) + NO2(g) is second-order in NO2 and zeroth-order in CO at temperatures less... Problem 22QRT: Nitrosyl bromide, NOBr, is formed from NO and Br2. 2NO(g)+Br2(g)2NOBr(g) Experiment shows that the... Problem 23QRT Problem 24QRT Problem 25QRT Problem 26QRT: For the reaction
these data were obtained at 1100 K:
Determine the order with respect to NO and... Problem 27QRT Problem 28QRT Problem 29QRT Problem 30QRT Problem 31QRT Problem 32QRT Problem 33QRT: For the reaction of phenyl acetate with water the concentration as a function of time was given in... Problem 34QRT: When phenacyl bromide and pyridine are both dissolved in methanol, they react to form... Problem 35QRT: The compound p-methoxybenzonitrile N-oxide, which has the formula CH3OC6H4CNO, reacts with itself to... Problem 36QRT Problem 37QRT: Radioactive gold-198 is used in the diagnosis of liver problems. 198Au decays in a first-order... Problem 38QRT Problem 39QRT Problem 40QRT Problem 41QRT Problem 42QRT Problem 43QRT Problem 44QRT Problem 45QRT Problem 46QRT Problem 47QRT Problem 48QRT Problem 49QRT Problem 50QRT Problem 51QRT Problem 52QRT Problem 53QRT: For the reaction of iodine atoms with hydrogen molecules in the gas phase, these rate constants were... Problem 54QRT Problem 55QRT: The activation energy Ea is 139.7 kJ mol1 for the gas-phase reaction HI+CH3ICH4+I2 Calculate the... Problem 56QRT Problem 57QRT Problem 58QRT Problem 59QRT Problem 60QRT Problem 61QRT Problem 62QRT Problem 63QRT Problem 64QRT: Which of the reactions in Question 62 would (a) occur fastest? (b) occur slowest? (Assume equal... Problem 65QRT Problem 66QRT Problem 67QRT Problem 68QRT Problem 69QRT Problem 70QRT Problem 71QRT Problem 72QRT: For the reaction the rate law is Rate=k[(CH3)3CBr] Identify each mechanism that is compatible with... Problem 73QRT Problem 74QRT Problem 75QRT Problem 76QRT: For this reaction mechanism,
write the chemical equation for the overall reaction.
write the rate... Problem 77QRT Problem 78QRT Problem 79QRT Problem 80QRT: When enzymes are present at very low concentration, their effect on reaction rate can be described... Problem 81QRT Problem 82QRT: The reaction is catalyzed by the enzyme succinate dehydrogenase. When malonate ions or oxalate ions... Problem 83QRT Problem 84QRT: Many biochemical reactions are catalyzed by acids. A typical mechanism consistent with the... Problem 85QRT Problem 86QRT Problem 87QRT Problem 88QRT Problem 89QRT Problem 90QRT Problem 91QRT Problem 92QRT Problem 93QRT Problem 94QRT Problem 95QRT: Nitryl fluoride is an explosive compound that can be made by oxidizing nitrogen dioxide with... Problem 96QRT Problem 97QRT Problem 98QRT: For a reaction involving the decomposition of a hypothetical substance Y, these data are... Problem 99QRT Problem 100QRT Problem 101QRT Problem 102QRT: This graph shows the change in concentration as a function of time for the reaction... Problem 103QRT Problem 104QRT Problem 105QRT Problem 106QRT Problem 107QRT Problem 108QRT Problem 109QRT Problem 110QRT Problem 111QRT Problem 112QRT Problem 113QRT Problem 114QRT Problem 115QRT Problem 116QRT Problem 118QRT Problem 119QRT Problem 120QRT: In a time-resolved picosecond spectroscopy experiment, Sheps, Crowther, Carrier, and Crim (Journal... Problem 121QRT: If you know some calculus, derive the integrated first-order rate law for the reaction
by following... Problem 122QRT: If you know some calculus, derive the integrated second-order rate law for the reaction 2Aproducts... Problem 11.ACP: (Section 11-5) A rule of thumb is that for a typical reaction, if concentrations are unchanged, a... Problem 11.BCP Problem 11.CCP Problem 11.DCP Problem 83QRT
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Concept explainers
One synthetic advantage of olefin metathesis is that the catalyst tolerates a variety of functional groups in the reactant. In a synthesis of the antiinfluenza drug Tamiflu (oseltamivir), ring-closing metathesis was used to prepare the highly functionalized cyclohexene derivative shown. What was the reactant?
Transcribed Image Text: HO
Si
Grubbs'
catalyst
CH2Cl2
NH
25°C
NH
Definition Definition Group of atoms that shape the chemical characteristics of a molecule. The behavior of a functional group is uniform in undergoing comparable chemical reactions, regardless of the other constituents of the molecule. Functional groups aid in the classification and anticipation of reactivity of organic molecules.
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