Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Consider a hypothetical chemical reaction:

→+AB+CD

(In this equation 

A, B, C and D

 stand for some unknown chemical formulas.)

 

Here is an energy diagram for the reaction:

 

Use the energy diagram to answer these questions.

What is the heat of reaction?
kJ/mol
Is the reaction exothermic or endothermic?
 
Exothermic
 
 
Endothermic
 
 
Neither
 
Can you determine the activation energy?
 
Yes,
 
it'skJ/mol
 
No.
 
Can you determine the activation energy of the reverse reaction?
 
Yes,
 
it'skJ/mol
→+CD+AB
 
No.
 
 
 
 
### Energy Diagram for a Chemical Reaction

#### Description

The diagram shown is an energy profile of a chemical reaction. On the y-axis, the energy is measured in kilojoules per mole (kJ/mol). The x-axis represents the reaction coordinate, which tracks the progress of the reaction from reactants to products.

#### Key Elements of the Diagram:

1. **Reactants**:
   - The starting point on the diagram is labeled \( A + B \).
   - At this point, the energy level is approximately 100 kJ/mol.

2. **Transition State**:
   - The peak of the diagram represents the transition state, where the energy is the highest.
   - The energy at this peak is around 400 kJ/mol.

3. **Products**:
   - The ending point on the diagram is labeled \( C + D \).
   - The energy level for the products is approximately 150 kJ/mol.

#### Explanation:

This energy diagram illustrates the energy change that occurs during the reaction from \( A + B \) to \( C + D \). Initially, the reactants \( A + B \) have an energy level of around 100 kJ/mol. As the reaction progresses, the system absorbs energy until it reaches the transition state with an energy of approximately 400 kJ/mol. After this peak, the energy decreases and stabilizes at 150 kJ/mol for the products \( C + D \).

This diagram shows that the reaction is **endothermic**, as the products have a higher energy (150 kJ/mol) compared to the reactants (100 kJ/mol).

Understanding such energy diagrams is crucial for grasping the concepts of activation energy and the energy profile of chemical reactions.
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Transcribed Image Text:### Energy Diagram for a Chemical Reaction #### Description The diagram shown is an energy profile of a chemical reaction. On the y-axis, the energy is measured in kilojoules per mole (kJ/mol). The x-axis represents the reaction coordinate, which tracks the progress of the reaction from reactants to products. #### Key Elements of the Diagram: 1. **Reactants**: - The starting point on the diagram is labeled \( A + B \). - At this point, the energy level is approximately 100 kJ/mol. 2. **Transition State**: - The peak of the diagram represents the transition state, where the energy is the highest. - The energy at this peak is around 400 kJ/mol. 3. **Products**: - The ending point on the diagram is labeled \( C + D \). - The energy level for the products is approximately 150 kJ/mol. #### Explanation: This energy diagram illustrates the energy change that occurs during the reaction from \( A + B \) to \( C + D \). Initially, the reactants \( A + B \) have an energy level of around 100 kJ/mol. As the reaction progresses, the system absorbs energy until it reaches the transition state with an energy of approximately 400 kJ/mol. After this peak, the energy decreases and stabilizes at 150 kJ/mol for the products \( C + D \). This diagram shows that the reaction is **endothermic**, as the products have a higher energy (150 kJ/mol) compared to the reactants (100 kJ/mol). Understanding such energy diagrams is crucial for grasping the concepts of activation energy and the energy profile of chemical reactions.
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