Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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- Cesium is used extensively in photocells and in television cameras because it has the lowest ionization energy of all the stable elements. (a) What is the maximum kinetic energy of a photoelectron ejected from cesium by 520 nm light? Note that if the wavelength of the light used to irradiate the cesium surface becomes longer than 660 nm, no photoelectrons are emitted. (b) Use the rest mass of the electron to calculate the velocity of the photoelectron in (a).arrow_forwardIn each of the following sets of elements, which element would he expected to have the highest ionization energy? msp;a.Cs,K,Lic.l,Br,Clb.Ba,Sr,Cad.Mg,Si,Sarrow_forwardConsider the following statement "The ionization energy for the potassium atom is negative, because when K loses an electron to become K +, it achieves a noble gas electron configuration." Indicate everything that is correct in this statement. Indicate everything that is incorrect. Correct the incorrect information and explain.arrow_forward
- Using the periodic table and without looking at Table 7.3, write electron configurations for the following elements: (a) P (b) Zn (c) Zr (d) In (e) Pb (f) U Use the spdf and noble gas notations. When you have finished, check your answers with Table 7.3.arrow_forward6.80 Describe how valence electron configurations account for some of the similarities in chemical properties among elements in a group.arrow_forwardWhich of the following statements is(are) true? a. F has a larger first ionization energy than does Li. b. Cations are larger than their parent atoms. c. The removal of the first electron from a lithium atom (electron configuration is ls2 2s1 ) is exothermic-that is, removing this electorn gives off energy. d. The He atom is larger than the H+ ion. e. The Al atorn is smaller than the Li atom.arrow_forward
- The energy needed to remove one electron from a gaseous potassium atom is only about two-thirds as much as that needed to remove one electron from a gaseous calcium atom, yet nearly three times as much energy as that needed to remove one electron from K+ as from Ca+ . What explanation can you give for this contrast? What do you expect to be the relation between the ionization energy of Ca+ and that of neutral K?arrow_forward(a) Predict the atomic number of the (as yet undiscovered) alkali-metal element in the eighth period. (b) Suppose the eighth-period alkali-metal atom turned out to have atomic number 137. What explanation would you give for such a high atomic number (recall that the atomic number of francium is only 87)?arrow_forwardAnswer the following questions, assuming that ms, could have three values rather than two and that the rules for n, l, and ml are the normal ones. a. How many electrons would an orbital be able to hold? b. How many elements would the first and second periods in the periodic table contain? c. How many elements would be contained in the first transition metal series? d. How many electrons would the set of 4f orbitals be able to bold?arrow_forward
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