)Given Ba C03 Bo"+ Carboncte anion is known to be hydrolyzed in the Cos the reaction, co- 3+ + H20 HCO3+ OH- Kbi - CHCO][ou] and, HCO3 + H20 H2C03 + OH Kb2 = [H) CO3][OH ] form. %3D THCO ] Since Ka, - 1.45 x 10, Kaz = 4.7x 10" and Ks Boco3 = 5.A x 4o-, 10-11 %3D %3D alculate the solubility of the Ba CO3 salt at pH =8 ond pH-12 depending -the PH value.
)Given Ba C03 Bo"+ Carboncte anion is known to be hydrolyzed in the Cos the reaction, co- 3+ + H20 HCO3+ OH- Kbi - CHCO][ou] and, HCO3 + H20 H2C03 + OH Kb2 = [H) CO3][OH ] form. %3D THCO ] Since Ka, - 1.45 x 10, Kaz = 4.7x 10" and Ks Boco3 = 5.A x 4o-, 10-11 %3D %3D alculate the solubility of the Ba CO3 salt at pH =8 ond pH-12 depending -the PH value.
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter4: Polar Bonds, Polar Reactions
Section: Chapter Questions
Problem 4E
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Step 1
The solubility product constant or the equilibrium constant is a measure of the extent to which the solute dissolves in the solvent, denoted by Ksp.
Solubility is the property of dissolution of a solute in a solvent to form a solution.
Generally, solubility increase with decreasing pH and it decreases with increasing pH.
Step 2
The given reaction,
Since either of [Ba2+][Ba2+] or [CO32−][CO32-] has the same concentration, substitute 's' for both of them.
Use an ICE table to find 's':
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