Give logical fragmentation reactions to account for the following ions observed in these mass spectra. (a) N-ethylaniline (PhNHCH2CH3): 121, 106, 77 (b) 1-bromo-2-methylbutane: 152, 150, 123, 121, 71 (base)

Give logical fragmentation reactions to account for the following ions observed in these mass spectra. (a) N-ethylaniline (PhNHCH2CH3): 121, 106, 77 (b) 1-bromo-2-methylbutane: 152, 150, 123, 121, 71 (base)

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter14: Mass Spectrometry

Section: Chapter Questions

Problem 14.29P

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Question

Give logical fragmentation reactions to account for the following ions observed in these mass spectra.

(a) N-ethylaniline (PhNHCH2CH3): 121, 106, 77

(b) 1-bromo-2-methylbutane: 152, 150, 123, 121, 71 (base)

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