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gas is at 24 ∘C. To what temperature must it be raised to triple

University Physics Volume 2

18th Edition

ISBN:9781938168161

Author:OpenStax

Publisher:OpenStax

Chapter2: The Kinetic Theory Of Gases

Section: Chapter Questions

Problem 71P: Find (a) the most probable speed, (b) the average speed, and (c) the rms speed for nitrogen...

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Concept explainers

Diatomic Gas

Molecule, is a collection of two or more atoms together (which constitute the smallest observable unit) into a pure material. There are some ways to represent the structure of a molecule. Factor symbols represent atoms in Lewis structures, and dots represent electrons that accompany them. A pair of mutual electrons (covalent bond) may be represented by a single dash. The ball-and-stick model depicts the spatial structure of the atoms better.

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A gas is at 24 ∘C.

To what temperature must it be raised to triple the rms speed of its molecules?

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Cylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.
Find (a) the most probable speed, (b) the average speed, and (c) the rms speed for nitrogen molecules at 295 K.
An ideal gas is contained in a vessel at 300 K. The temperature of the gas is then increased to 900 K. (i) By what factor does the average kinetic energy of the molecules change, (a) a factor of 9, (b) a factor of 3, (c) a factor of 3, (d) a factor of 1, or (e) a factor of 13? Using the same choices as in part (i), by what factor does each of the following change: (ii) the rms molecular speed of the molecules, (iii) the average momentum change that one molecule undergoes in a collision with one particular wall, (iv) the rate of collisions of molecules with walls, and (v) the pressure of the gas?
One cylinder contains helium gas and another contains krypton gas at the same temperature. Mark each of these statements true, false, or impossible to determine from the given information. (a) The rms speeds of atoms in the two gases are the same. (b) The average kinetic energies of atoms in the two gases are the same. (c) The internal energies of 1 mole of gas in each cylinder are the same. (d) The pressures in the two cylinders ale the same.
How many moles are there in (a) 0.0500 g of N2 gas (M = 28.0 g/mol)? (b) 10.0 g of CO2 gas (M = 44.0 g/mol)? (c) How many molecules are present in each case?
Consider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANS
Fifteen identical particles have various speeds: one has a speed of 2.00 m/s, two have speeds of 3.00 m/s, three have speeds of 5.00 m/s, four have speeds of 7.00 m/s, three have speeds of 9.00 m/s, and two have speeds of 12.0 m/s. Find (a) the average speed, (b) the rms speed, and (c) the most probable speed of these particles.
The pressure gauge on a cylinder of gas registers the gauge pressure, which is the difference between the interior pressure and the exterior pressure P0. Lets call the gauge pressure Pg. When the cylinder is full, the mass of the gas in it is mi at a gauge pressure of Pgi. Assuming the temperature of the cylinder remains constant, show that the mass of the gas remaining in the cylinder when the pressure reading is Pgf is given by mf=mi(Pgf+P0Pgi+P0)