free radical and the pi cloud holding the electron are directed away from each other because of the formation of a halonium ion which sterically blocks one side of the compound thus the other side is open for attack because the halogen should occupy both sides to accommodate the pi clouds None of the above Two equivalents of HCl are added to an alkyne, where do you expect to see the Cl atom? The two Cl atoms will be distributed between the two Carbon atoms involved in the triple bond The two Cl atoms forms a bond with the less substituted carbon

Chemistry by OpenStax (2015-05-04)
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Chapter12: Kinetics
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In halogenation reactions, why are halogens added on opposite sides of the compound?

  • because the reaction proceeds via free radical and the pi cloud holding the electron are directed away from each other
  • because of the formation of a halonium ion which sterically blocks one side of the compound thus the other side is open for attack
  • because the halogen should occupy both sides to accommodate the pi clouds
  • None of the above

Two equivalents of HCl are added to an alkyne, where do you expect to see the Cl atom?

  • The two Cl atoms will be distributed between the two Carbon atoms involved in the triple bond
  • The two Cl atoms forms a bond with the less substituted carbon
  • Both Cl atoms attach to one carbon, which is the more substituted one
  • A mixture of products are formed
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