Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- For the reaction: 24(g) +B(s)=2C(s) + D(g)Kp = 8210 At 250K in a 10.0L vessel, the known equilibrium values are follows: 0.030atm of A, 0.22mol of B, and 10.5mol of C. What is the equilibrium partial pressure of D ?arrow_forwardConsider the following equilibrium: 2NOC1 (g) 2NO(g) + Cl₂ (g) AG=41. KJ Now suppose a reaction vessel is filled with 3.76 atm of nitrosyl chloride (NOC1) and 6.26 atm of nitrogen monoxide (NO) at 1161. °C. Answer the following questions about this system: Under these conditions, will the pressure of NO tend to rise or fall? Is it possible to reverse this tendency by adding C1₂? In other words, if you said the pressure of NO will tend to rise, can that be changed to a tendency to fall by adding C1₂? Similarly, if you said the pressure of NO will tend to fall, can that be changed to a tendency to rise by adding Cl₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of C12 needed to reverse it. Round your answer to 2 significant digits. OO rise fall yes no atm x10 X Śarrow_forwardFor the reaction 2 SO2 (g) + O2 (g) <=> 2 SO3 (g), at 250oC the equilibrium mixture contains 0.60 atm SO2, 1.3 atm O2, and 2.1 atm SO3. Determine Kp for this reaction.arrow_forward
- Consider the reaction SbH5 (g) SbH3 (g) + H2 (g) If 0.500 atm of SbH5 is introduced into an empty, closed container at 248oC and the system is allowed to reach equilibrium, 0.397 atm of SbH5 remains. Find Kp and Kc.arrow_forward3. Phosphoryl chloride, POCI3(g), is used in the manufacturing of flame retardants. It is manufactured in an equilibrium process in which phosphorus trichloride reacts with nitrogen dioxide to form POCI3(8)and NO(g) according to the following equation: PCI3 (g) + NO2 (g) = POCI3 (g) + NO (g) The Keg for this reaction at 800 K is 6.90. If 1.25 mol PCI3 (g) and 1.94 mol NO2 (g) are placed into a 2.0 L container, what is the concentration of each gas at equilibrium at 800 K? PCI3 (g) NO2 (g) POCI3 (g) NO(g) Keq = 6.90 + + Earrow_forwardA reaction vessel initially contains 6.30 atm of A and 2.10 atm of B. A reaction occurs according to the equation:2A(g)+B(g)⇆2C(g)2A(g)+B(g)⇆2C(g)When equilibrium is reached, the total pressure is found to be 6.51 atm. What is the equilibrium constant Kp?Please enter your response to three significant figures using decimal notation.arrow_forward
- For which one of the following reactions is Kp equal to Kc? CaCO3(s) = CaO(s) + CO₂(g) 2NH3(g) = 3H₂(g) + N₂(g) 302(g) = 203(g) SnO2(s) + 2H₂(g) Sn(s) + 2H₂O(g) NH41(s) NH3(g) + HI(g)arrow_forward8. Consider the equilibrium reaction: N2(g) + O2(g) = 2 NO(g) Kp 4.10 x 10³ at 2000°C a) If 1.00 atm of nitrogen gas and 1.00 atm of oxygen gas is mixed with 0.10 atm of nitrogen monoxide in a 500.0 mL container at 2000°C, in which direction will the reaction proceed to reach equilibrium? Show all work to justify your answer. b) What is the concentration of each gas when equilibrium is reached at 2000°C? Show all your work. Equilibrium Partial Pressures: PN₂ = Po₂ = 1.02 atm and PNO = 0.07 atm Use PV = nRT Answer: Equilibrium Concentrations: [N₂] = [0₂] = 5.47 x 10-3 mol/L and [NO] = 4 x 10+ Marrow_forwardFor the following reaction: NH4Cl(s) ↔ NH3(g) + HCl(g) ΔH = +42.1 kilocalories Suppose the substances in the reaction above are at equilibrium at 600K in volume V and at pressure P. State whether the partial pressure of NH3(g) will have increased, decreased, or remained the same when equilibrium is reestablished after each of the following disturbances of the original system. Some solid NH4Cl remains in the flask at all times. Justify each answer with a one-or-two sentence explanation. (e) A quantity of gaseous NH3 is added. The answer for e states that the partial pressure of NH3 is increase, which is a bit confusing. The explanation is that some of the the added NH3 reacts with HCl to relieve stress but only part of NH3 reacts. Can you explain how and where this is implied in the reaction or question. Would appreciate a lot of clarificationarrow_forward
- For the gas-phase equilibrium A(g) + 2 B(g) = C(g) the initial partial pressures of A, B, and C are all 0.300 atm. After equilibrium is established at 25°C, it is found that the partial pressure of C is 0.270 atm. What is AG° for this reaction? (R = 8.314 J/mol · K). kJ/mol 1 3 4 C 7 8 9 +/- x 100 + 2.arrow_forwardConsider the following exothermic reaction, used to obtain lead from its ore:2PbS (s) + 3O2 (g) + 2CO (g) ↔ 2 Pb (l) + 2SO2 (g) + 2CO2 (g)Assume that this reaction is in equilibrium. Given the following changes to the system, will the quantity of lead increase, decrease, or remain the same?i) adding more lead sulfide.ii) Adding more carbon monoxide.iii) removing some oxygen.arrow_forward
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