For each of the following pairs, use HSAB theory to predict which Lewis acid-base adduct would be more stable. For the more stable adduct, predict whether the interaction will be more covalent or more ionic in nature. PbI2 PbF2 LiF LiCl AlCl3 AlI3

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Chapter1: Chemical Foundations
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For each of the following pairs, use HSAB theory to predict which Lewis acid-base adduct would be more stable. For the more stable adduct, predict whether the interaction will be more covalent or more ionic in nature.

 

  1. PbI2                  PbF2
  2. LiF                    LiCl
  3. AlCl3                 AlI3
  4. Ni(CO)4            Ni(H2O)
  5. [Ag(S2O3)2]2-   [Ag(NH3)2]+
  6. [AlF6]3–            [AlBr6]3–
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