For each of the following molecules, identify the number of ¹H NMR signals you expect to see and their accompanying splitting patterns. Shown below is an example from class of how you can write your answers. Example answer a. b. H H H. MS H HH H H quartet singlet triplet Total number of signals: 3 List splitting patterns here (and label on molecule): singlet, quartet, triplet مگر Total number of signals: List splitting patterns here (and label on molecule): Total number of signals: List splitting patterns here (and label on molecule):

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Order these chemical species by increasing pH of an 0.1 M aqueous solution of each. That is, imagine making an 0.1 M solution of each species. Select 1 next to the species that makes the solution with the lowest pH. Select 2 next to the species that makes the solution with the next higher pH, and so on. Notice that some of the rankings have been filled in for you already. Also notice that water is on the list. For that particular case, just compare the pH of pure water to the pH of the other solutions. Note for advanced students: for all charged species, you may assume the necessary counterions act as neither acids nor bases. relative pH of 0.1 M aqueous solution species H20 4 H,PO4 5 HNO2 (Choose one) ▼ NO, 7 ОН (Choose one) ▼ HF |(Choose one) ▼