following reaction. PH3BCl3(s)  PH3(g) + BCl3(g) (a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel and decomposes until equilibrium is reached. [PH3]   M [BCl3]   M

Consider the reaction, 2AB2(g) = A2(g) + 2B2(g), Kc = 0.263 at 25°C. The reaction begins with an unknown concentration of AB2 in the reaction flask. At equilibrium, the concentration of AB2 is found to be 0.00545 M. a) Complete the ICEE table below, b) Write the equilibrium expression and equation for this reaction (pay close attention to coefficients!), c) Calculate the equilibrium concentration of both products, and d) Calculate the initial concentration of AB2. You should confirm that your equilibrium concentrations will give the correct equilibrium constant when plugged into the expression. ICEE table I C E 2 AB₂(g) A₂(g) + 2 B₂(g)

Iodine and bromine react to give iodine monobromide, IBr. I1 (9) + Brz (9) = 2IB:(9) What is the equilibrium composition of a mixture at 154°C that initially contained 1.10 x 10- mol each of iodine and bromine in a 5.00 L vessel? The equilibrium constant K, for this reaction at 154°C is 130. [1:] =( M [Bra] =( M [IBr] = M

(b) At 100° C, the Keq for the Haber process is 4,51 X 10-5: N₂ + 3 H₂ 2 NH3 Consider the following reaction conditions and determine if the system is at equilibrium. If not, indicate the direction in which the reaction must proceed to establish equilibrium (i) PNH3 105 atm, PN2 = 35 atm and PH2 = 495 atm (ii) PNH3 35 atm, PN2 = 0 atm and PH2 = 595 atm (iii) PNH3 = 26 atm, PN2 = 202 atm and PH2 = 42 atm (iv) PNH3 105 atm, PN2 = 5 atm and PH2 = 55 atm