Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Concept explainers

Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reacti…
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carboc…
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond t…
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthes…
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
Question

Fill in the missing products for when the following molecules are reacted with various reagents.

The image shows a chemical transformation diagram involving a hexose molecule. The structure of the hexose is labeled with carbon numbers (1 through 6) and displays hydroxyl groups (OH) attached to each carbon. - **Reagents and Reaction Conditions:** - An arrow pointing upwards is labeled with two reagents: 1. SOCl₂ (thionyl chloride) 2. COONa (sodium carboxylate) - **Additional Information:** - To the left of the hexose structure, "PCC" (pyridinium chlorochromate) is noted, often used for oxidation in organic chemistry. - To the right of the structure, "Jones" is mentioned, referring to Jones oxidation, a method using chromium trioxide (CrO₃) in sulfuric acid, which oxidizes alcohols to carboxylic acids. This setup likely represents a proposed synthetic pathway involving oxidation and substitution reactions to modify the hydroxyl groups on the hexose ring.
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Transcribed Image Text:The image shows a chemical transformation diagram involving a hexose molecule. The structure of the hexose is labeled with carbon numbers (1 through 6) and displays hydroxyl groups (OH) attached to each carbon. - **Reagents and Reaction Conditions:** - An arrow pointing upwards is labeled with two reagents: 1. SOCl₂ (thionyl chloride) 2. COONa (sodium carboxylate) - **Additional Information:** - To the left of the hexose structure, "PCC" (pyridinium chlorochromate) is noted, often used for oxidation in organic chemistry. - To the right of the structure, "Jones" is mentioned, referring to Jones oxidation, a method using chromium trioxide (CrO₃) in sulfuric acid, which oxidizes alcohols to carboxylic acids. This setup likely represents a proposed synthetic pathway involving oxidation and substitution reactions to modify the hydroxyl groups on the hexose ring.
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