
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Explain the term dielectric constant.
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- The standard free energy change for a reaction can be calculated using the equation ΔG∘′=−nFΔE∘′ where n is the number of electrons transferred, F is Faraday's constant, 96.5 kJ·mol−1·V−1, and ΔE∘′ is the difference in reduction potential. For each of the given reactions, determine the number of electrons transferred (n) and calculate standard free energy (ΔG∘′) . Consider the half-reactions and overall reaction for reaction 1. half-reactions: fumarate^2− + 2H^+ ↽−−⇀ succinate^2− CoQH2 ↽−−⇀ CoQ + 2H^+ overall reaction: fumarate^2− + CoQH2↽−−⇀succinate^2− + CoQ ΔE∘′= −0.009 V n=____ ΔG∘′= ____ (kJ⋅mol^−1) Consider the half-reactions and overall reaction for reaction 2. half-reactions: cytochrome (c1) (Fe^2+) ↽−−⇀ cytochrome (c1) (Fe^3+) cytochrome (c) (Fe^3+) ↽−−⇀ cytochrome (c) (Fe^2+) overall reaction: cyt (c1) (Fe^2+)+cyt (c) (Fe^3+)↽−−⇀cyt (c1) (Fe^3+)+cyt (c) (Fe^2+) ΔE∘′=0.034 V n= ____ ΔG∘′=____(kJ⋅mol^−1)arrow_forwardDiscuss the groups of chemical elements that are the most active. give examples or explanation.arrow_forward
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