
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Calculate ∆H for the reaction 4 NH3 (g) + 5 O2 (g) → 4 NO (g) + 6 H2O (g), from the following data. K2 T2 A2 C2 ∙ N2 (g) + O2 (g) → 2 NO (g) ∆H = ‐180.5 kJ ∙ N2 (g) + 3 H2 (g) → 2 NH3 (g) ∆H = ‐91.8 kJ ∙ 2 H2 (g) + O2 (g) → 2 H2O (g) ∆H = ‐483.6 kJarrow_forwardA substance has a molar specific heat, cV,m=4.00 J K-1mol-1and a molar mass, M=10.0 g/mol. A 100.0 g sample of this substance (Sample 1) was cooled to 250.0 K, while a 1.000 kg sample of the same substance (Sample 2) was heated to 400.0 K. Assume that for temperatures between 250.0 K and 400.0 K, the substanceremains in the same thermodynamic phase, i.e, no phase transition takes place. Suppose that the wall separating the two samples is now made diathermal, but remains impermeable and rigid. Suppose that the two samples form an isolated system. The samples are then observed one week later. What are the temperatures of samples 1 and 2?arrow_forwardExplain the difference between macrostates and microstates?arrow_forward
- 8 a) -511.3 kJ B) +511.3 kJ NS) -697.5kJ D) +697.5kJ TO) -47.3 kJarrow_forwardHow could the calculated enthalpy be used to determine the minimum entropy required for a spontaneous process? Why is this known to be the minimum required entropy?arrow_forwardWhat happens to the entropy of an isolated system during an irreversible process?arrow_forward
- Entropy is the randomness of a system. At the molecular level, entropy can be described in terms of the possible number of different arrangements of particle positions and energies, called microstates. The more microstates the system has, the greater its entropy. Another way of looking at entropy is that the universe is moving toward a broader distribution entropy has since been constantly increasing by distributing this energy. Heat distribution from high temperature to low temperature is a another example of this phenomenon. energy. The universe has a constant amount of energy as stated in the first law of thermodynamics. The universe started with low entropy (concentrated in the moment before the "big bang") and the Part A Rank these systems in order of decreasing entropy. Rank from highest to lowest entropy. To rank items as equivalent, overlap them. > View Available Hint(s) Reset Help Greatest entropy Least entropy 1 mol of helium gas at 273 K and 20L 1 mol of 1 mol of helium gas…arrow_forward15. In which of the following systems is(are) work done by the surroundings on the system? AsSsume pressure and tempera- ture are constant. a. 2S0,(g) + 0,lg) → b. CO,(s) c. 4NH,(g) + 70,(g) → 4NO,(g) + 6H,O(g) d. N,O,(g) e. CACO;(s) –→ CaCO(s) + CO,(g) → 2S03(g) CO,(g) > → 2NO,(g) >arrow_forwardΔHrxn∘=− 85 kJ, ΔSrxn= 154 J/K, T= 392 K Find ΔSunivarrow_forward
- Calculate for the Delta H (enthalpy) of the reaction below given the following data: 2NH3(g) + 3N₂O(g) →→→ 4N₂(g) + 3H₂O(l) N₂O(g) + 3H₂(g) →N₂H4(l) + H₂O(l) N₂H4(l) + O₂(g) H₂(g) + O₂(g) -141 kJ -163 kJ -450 kJ +356 kJ +150 kJ -131 kJ 2NH3(g) + O₂(g) →→→→N₂H4(1) + H₂O(l) -231 kJ - N₂(g) + 2H₂O(l) H₂O(l) AH-1010. kJ AH = -317 kJ AH = -623 kJ AH = -286 kJarrow_forwardCalculate the ∆H°rxn for the reaction C(graphite) + 2H2(g) → CH4(g)from the following enthalpy changes: - Cgraphite + O2(g) → CO2(g) ∆H = -393.5 kJ - 2H2(g) + O2(g) → 2H2O(l) ∆H = -571.6 kJ - CH4(g) + 2O2(g) → CO2(g) + 2H2O(l) ∆H = -890.4 kJarrow_forwardDoarrow_forward
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