EXPERIMENTAL RXN:- Mechanism - A (2 Preparation of Nickel Thiocyanate Solution :- When Ni(NO2),. 6H2O is dissolved in n-butanol: 2+ Ni(NO3)2 6H20 n-butanol, Ni² + + 2 NO₂ + 6H₂O. Then (heat) - Add Potassium thiocyanate (KSCN) to hot Ni (NO3)2 6H20 Solution, then it will produce Nickle thiocyanate in Solution & Precipitation of Potassium Nitrate (KNO3) Rx":- N2+ +2NCS → Ni(SCN)2 2KN03 (ppt) 2K+ + 2N03 Live To Prepare Triphenylphosphine in Sol?:- When Triphenylphosphine (PPh3) is dissolved in n-butanol by heating. Rxn- PPh 3 (s) n-butanol, PPh3 (Solution). liii formation of Dithiocyanatobis (triphenyl phosphine) Liis Nickel (11) (Ni(NCS), (PPh3)2} signdor M Add hot triphenylphosphine Solution to hot Nickel throcyanate Solution: (i) RxNi-wil 21 Octafsil 21° * Ni(NCS) +2PPh3 (Solution) [Ni(NCS), (PPho)] Tonstud-r Overall RXN: लता 11 stranussid muizenty bb Ni (NO3)2.6H₂O + 2 KNCS +2PPh31 >[Ni(SCN)2 (PPh3)2] + 2KN03+6H20 42214 2016

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partA. Can u it both images compurize please like use chem drawing software use it computerize drawing my handwriting okk
EXPERIMENTAL RXN:-
Mechanism -
A
(2 Preparation of Nickel Thiocyanate Solution :-
When Ni(NO2),. 6H2O is dissolved in
n-butanol:
2+
Ni(NO3)2 6H20 n-butanol, Ni² + + 2 NO₂ + 6H₂O.
Then
(heat)
- Add Potassium thiocyanate (KSCN) to hot
Ni (NO3)2 6H20 Solution, then it will
produce Nickle thiocyanate in Solution &
Precipitation of Potassium Nitrate (KNO3)
Rx":-
N2+
+2NCS
→ Ni(SCN)2
2KN03 (ppt)
2K+ + 2N03
Live To Prepare Triphenylphosphine in Sol?:-
When Triphenylphosphine (PPh3) is dissolved
in n-butanol by heating.
Rxn-
PPh 3 (s) n-butanol, PPh3 (Solution).
Transcribed Image Text:EXPERIMENTAL RXN:- Mechanism - A (2 Preparation of Nickel Thiocyanate Solution :- When Ni(NO2),. 6H2O is dissolved in n-butanol: 2+ Ni(NO3)2 6H20 n-butanol, Ni² + + 2 NO₂ + 6H₂O. Then (heat) - Add Potassium thiocyanate (KSCN) to hot Ni (NO3)2 6H20 Solution, then it will produce Nickle thiocyanate in Solution & Precipitation of Potassium Nitrate (KNO3) Rx":- N2+ +2NCS → Ni(SCN)2 2KN03 (ppt) 2K+ + 2N03 Live To Prepare Triphenylphosphine in Sol?:- When Triphenylphosphine (PPh3) is dissolved in n-butanol by heating. Rxn- PPh 3 (s) n-butanol, PPh3 (Solution).
liii formation of Dithiocyanatobis (triphenyl phosphine)
Liis
Nickel (11)
(Ni(NCS), (PPh3)2}
signdor M
Add hot triphenylphosphine Solution to
hot Nickel throcyanate Solution: (i)
RxNi-wil 21 Octafsil
21°
*
Ni(NCS) +2PPh3 (Solution)
[Ni(NCS), (PPho)]
Tonstud-r
Overall RXN:
लता
11 stranussid muizenty bb
Ni (NO3)2.6H₂O + 2 KNCS +2PPh31
>[Ni(SCN)2 (PPh3)2] + 2KN03+6H20
42214
2016
Transcribed Image Text:liii formation of Dithiocyanatobis (triphenyl phosphine) Liis Nickel (11) (Ni(NCS), (PPh3)2} signdor M Add hot triphenylphosphine Solution to hot Nickel throcyanate Solution: (i) RxNi-wil 21 Octafsil 21° * Ni(NCS) +2PPh3 (Solution) [Ni(NCS), (PPho)] Tonstud-r Overall RXN: लता 11 stranussid muizenty bb Ni (NO3)2.6H₂O + 2 KNCS +2PPh31 >[Ni(SCN)2 (PPh3)2] + 2KN03+6H20 42214 2016
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