Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Expectation: investigate the qualitative and quantitative nature of chemical systems at equilibrium, and solve related problems.
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- Give 3 examples of chemical equilibrium expressions that are important to day-to-day life/activities and explain their relevance.arrow_forwardA mixture of 0.5910 M CO and 0.3570 M Cl, is enclosed in a vessel and heated to 1000 K. CO(g) + Cl,(g) = COCI,(g) K. = 255.0 at 1000 K Calculate the equilibrium concentration of each gas at 1000 K. [CO] = M [CI,] = M [COCI,] = Marrow_forwardExpectation: investigate the qualitative and quantitative nature of chemical systems at equilibrium, and solve related problems.arrow_forward
- The equilibrium constant, K., is calculated using molar concentrations. For gaseous reactions another form of the equilibrium constant, Kp, is calculated from partial pressures instead of concentrations. These two equilibrium constants are related by the equation K₂ = K. (RT)An where R = 0.08206 L-atm/(K-mol), T is the absolute temperature, and An is the change in the number of moles of gas (sum moles products - sum moles reactants). For example, consider the reaction N₂(g) + 3H₂(g) = 2NH3(g) for which An=2-(1+3) = -2.arrow_forwardPlease provide detailed solution...arrow_forwardSuppose a 500. mL flask is filled with 0.90 mol of NO, and 1.8 mol of NO,. The following reaction becomes possible: NO, (g) +NO(g) - 2NO, (g) The equilibrium constant K for this reaction is 5.58 at the temperature of the flask. Calculate the equilibrium molarity of NO. Round your answer to two decimal places. ©2022 McGraw Hill LLC. All Rights Reserved. Terms 43,203 FEB 19 PP ESS MacBook Airarrow_forward
- Consider the following chemical equilibrium: CaCO; (s)= CaO ()+CO, (g) Now write an equation below that shows how to calculate K, from K, for this reaction at an absolute temperature 7. You can assume T is comfortably above room temperature. If you include any common physical constants in your equation be sure you use their standard symbols, found in the ALEKS Calculator.arrow_forwardA mixture of 0.04289 mol of C2H4, 0.08501 mol of N2, 0.02401 mol of NH3, and 0.05848 mol of C6H6 is placed in a 1.0-L steel pressure vessel at 1258 K. The following equilibrium is established: 3 C2H4(g) + 1 N2(g) 2 NH3(g) + 1 C6H6(g) At equilibrium 0.005819 mol of NH3 is found in the reaction mixture.(a) Calculate the equilibrium partial pressures of C2H4, N2, NH3, and C6H6.Peq(C2H4) = .Peq(N2) = .Peq(NH3) = .Peq(C6H6) = .(b) Calculate KP for this reaction.KP = .arrow_forwardthe equilibrium constant (K) is a quantitative measurement of theextent to which a chemical or physical reaction proceeds to completion. If two reactants ofknown initial concentration are mixed and then the concentrations of the products aremeasured once equilibrium has been established, then the equilibrium constant can becalculated using an ICE table.In this experiment you will measure the equilibrium constant for the formation of iron(III)thiocyanate from the iron(III) cation and thiocyanate anion:Fe3+(aq) + SCN-(aq) FeSCN2+(aq)The product, FeSCN2+, is intensely red, which means that its concentration can be measured byusing an ultraviolet-visible (UV-vis) spectrophotometer. So long as a solution is not tooconcentrated, the absorption of light at a particular wavelength by a chemical species isdescribed by Beer’s Law:A = εℓ[X] where A = absorption of light (unitless number)ε = molar absorptivity constant (cm-1 M-1)ℓ = path length (cm)[X] = concentration (M)The path length for our…arrow_forward
- Consider the reaction of N₂O and O2 described by the chemical reaction below. Determine the equilibrium constant for this reaction by constructing an ICE table, writing the equilibrium constant expression, and solving it. Complete Parts 1-2 before submitting your answer. NEXT > A 1.00 L reaction vessel was filled with 0.0560 mol O₂ and 0.200 mol N₂O and allowed to react at 298 K. At equilibrium, there were 0.0200 mol of NO2 present. Fill in the ICE table with the appropriate value for each involved species to determine concentrations of all reactants and products.. Initial (M) Change (M) Equilibrium (M) 0.0100 0.0410 0 -0.0100 0.0710 1 2 N₂O(g) + 3 O₂(g) = 4 NO2(g) 2N₂O(g) 0.0560 -0.0050 0.0360 0.200 0.0050 0.180 + -1.00 0.0150 30₂(g) 2 -0.0560 -0.0150 0.0200 0.210 4NO₂(g) RESET -0.0200 0.190 +arrow_forwardA mixture of 0.5110 M CO and 0.3590 M Cl, is enclosed in a vessel and heated to 1000 K. CO(g) + Cl, (g)= COCI,(g) K. = 255.0 at 1000 K Calculate the equilibrium concentration of each gas at 1000 K. [CO] = M %3D [CI,] = M [COCI,] = Marrow_forwardAt 100 °C, Keg = 1.5E8 for the reaction: CO(g) + Cl2(g) - COCI2(g) Using appropriate approximation, calculate the partial pressure of CO at 100 °C at equilibrium in a chamber that initially contains COCI2 at a pressure of 0.302 bar.arrow_forward
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