Draw the structure(s) of the major organic product(s) of the following reaction. 1. lithium diisopropylamide/ hexane Br 2.1 eq. You do not have to consider stereochemistry. • Omit products derived from the acidic or basic reagent itself, e.g. HN(i-Pr)2 derived from N(i-Pr)2. If no reaction occurs, draw the organic starting material. If substantial starting material is present at the end of the reaction, include it in the products. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu. ChemDoodle کر 8

ORT SHEET Heat of Neutralization EXPERIMENT elemsboomfchg lom 12 A. Heat Capacity of Calorimeter 1. Temp. of calorimeter and water before mixing 2. Temp. of warm water °C 22.0 39,0 30.3 3. Maximum temp. determined from your curve °C 4. Heat lost by warm water (temp decrease x °C 50.0 g x 4.184 J/K-g) = 02), 5. Heat gained by cooler water (temp. increase x 50.0 g x 4.184 J/K-g) = 30,3 22.0)x 13626J s0.0gmpi S0.0gy 6. Heat gained by the calorimeter [(4) – (5)] = 7. Heat capacity of calorimeter: heat gained by the calorimeter temperature increase J/K 3. Heat of Neutralization of HCl-NaOH 22.2 22.2. °C . Temp. of calorimeter and NaOH Temp. of HCI AT determined from your curve after adding HC1 °C to the NaOH Heat gained by solution (temperature increase x ON 100 g x 4.184 J/K-g) = 9977.8J %3D Heat gained by calorimeter (temperature increase x heat capacity of calorimeter) = J %3D Total joules released by reaction [(3) + (4)] = Tight O 2018 Pearson Education, Inc.

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CI Cl2 heat 8⁰ (1) (2) (3) Based on your results for the radical chlorination experiment, predict which products would be most and least abundant in the product mixture. Briefly justify your answer. CI

1) NaOEt 2) Br 3) H3O*, heat

[Review Topics] [References] Use the References to access important values if needed for this question. Ethanol, C2H,O, is most often blended with gasoline - usually as a 10 percent mix - to create a fuel called gasohol. Ethanol is a renewable resource and ethanol-blended fuels, like gasohol, appear to burn more efficiently in combustion engines. The heat of combustion of ethanol is 326.7 kcal/mol. The heat of combustion of hexane, C,H14, is 995.0 kcal/mol. How much energy is released during the complete combustion of 479 grams of hexane ? kcal Assuming the same efficiency, would 479 grams of ethanol provide more, less, or the same amount of energy as 479 grams of hexane? Submit Answer Retry Entire Group 9 more group attempts remaining

Primary reaction product

500.0 mL of 0.100 mol·L HCl(aq) was added to a high quality insulated calorimeter containing 500.0 mL of 0.100 mol·LNaOH(aq). Both solutions had a density of 1.000 g·mL and a specific heat of 4.184 J·g ·K . The calorimeter had a heatcapacity of 850.0 J·K . The temperature of the entire system rose from 25.50 C to 26.05 C.Calculate the heat of reaction.   Thank you!

Name these organic compounds: Η Η Η Η Η Η ||| C=C=C-H ||| Η Η Η Η Η II H — C =C=C=C=C - H ||||| Η structure Η Η Η Η Η Η H H Η Η Η | Η ||| H – C – C =C=C=C=C=CH ||||||| Η Η Η Η Η Η Η name Π Π Π

Order these chemical species by increasing pH of an 0.1 M aqueous solution of each. That is, imagine making an 0.1 M solution of each species. Select1 next to the species that makes the solution with the lowest pH. Select 2 next to the species that makes the solution with the next higher pH, and so on. Notice that some of the rankings have been filled in for you already. Also notice that water is on the list. For that particular case, just compare the pH of pure water to the pH of the other solutions. Note for advanced students: for all charged species, you may assume the necessary counterions act as neither acids nor bases. relative pH of 0.1 M aqueous solution species H20 4 H,PO4 HNO, (Choose one) NO2 7 OH (Choose one) HF (Choose one) ▼