Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Enthalpy of Reaction: Question #5 Methanol, CH3OH, is a possible fuel for automobiles. Energy is evolved in its combustion with oxygen, O2 → 2 CO2(g) 2 CH3OH(9) + 3 O2(9) kJ 2 mol CH3OH(g) + 4 H2O) AH°, rxn A 0.0466-g sample of methanol evolves 1110 J of heat when burned with oxygen at constant pressure. a) What is the enthalpy change (AH rxn) for this reaction (kJ/ 2 mol CH3OH(g) )? AH°rxn = - 1530 kJ/ 2 mol CH3OH(g) >arrow_forwardConsider the reaction of calcium carbide with liquid water: 1/2 CaC2(s) + H2O(l) 1/2 Ca(OH)2(s) + 1/2 C2H2(g) H = -63.6 kJ (a) What is the enthalpy change for the reverse reaction?(b) Balance the forward reaction with whole-number coefficients. What is H for the reaction represented by this equation?(c) Which is more likely to be thermodynamically-favored, the forward reaction or the reverse reaction? (d) If the (forward) reaction were written to consume water gas, H2O(g), instead of liquid water, would you expect the magnitude of H to increase (become more positive), decrease (become more negative), or stay the same?arrow_forwardCarbon disulfide is a colorless liquid. When pure, it is nearly odorless, but the commercial product smells vile. Carbon disulfide is used in the manufacture of rayon and cellophane. The liquid burns as follows: CS2 (1) +302 (9) → CO2(9) + 2SO2 (g) Calculate the standard enthalpy change for this reaction using standard enthalpies of formation. AH;(CS2 (1)) = 89.70 kJ/mol AH;(02(9)) = 0 kJ/mol %3D AH;(CO2 (g)) =-393.52 kJ/mol AH;(SO2 (g)) =-296.8 kJ/mol %3D Standard enthalpy change = kJarrow_forward
- You wish to find the enthalpy for the reaction 6 Gel (s) + 14 NH:1 (s) → 3 Ge:H6 (1) + 7 N2 (g) + 38 HI (g) kJ/mol Given the following equations Equation 1: 2 Ge (s) + 3 H2 (g) → Ge:H6 (1) AH = 137.3 kJ/mol Equation 2: Ge (s) + 4 HI (g) – Gel: (s) + 2 H2(g) AH = -247.8 kJ/mol Equation 3: 2 NH&| (s) → N2 (g) + 2 HI (g) + 3 H2(g) AH = 455.8 kJ/mol 2 4 C What would be the enthalpy change, in kJ/mol, for 6 Gel4 (s) + 12 H2(g) - 6 Ge (s) + 24 HI (g)? 7 8 9. +/- x 100 3. 1,arrow_forwardThe standard heat of formation, AH, is defined as the enthalpy change for the formation of one mole of substance from its constituent elements in their standard states. Thus, elements in their standard states have AH = 0. Heat of formation values can be used to calculate the enthalpy change of any reaction. Part A For which of the following reactions is AH equal to AH of the product(s)?You do not need to look up any values to answer this question !3! Check all that apply. Consider, for example, the reaction > View Available Hint(s) 2NO(g) + O2(g) = 2NO2(g) with heat of formation values given by the following table: O 2Na(s) + Ch (x)-2NACI(s) O H,O, (g)→02(g) + H,O(g) AH (kJ/mol) Substance NO(g) - Na(s) +C½(1)¬NACI(s) 90.2 O2(g) O 2H,(g) + O2(g)--2H,O(g) NO2 (g) 33.2 O H2(g) + 0,(g)→H,O(g) Then the standard heat of reaction for the overall reaction is o Na(s) +Cl, (g)¬NACI(s) AH= AH; (products)- AH (reactants) 2(33.2) 12(90.2) + 0) Submit Previous Answers Request Answer 114 kJ P Pearson…arrow_forwardGiven the following standard enthalpy change, use the standard enthalpies of formation in slide 51(Table 5.3 in chapter 5) to calculate the standard enthalpy of formation of CuO(s): CuO(s) + H2 (g) → Cu(s) + H20 (I) AH° = -129.7 kJ Use the editor to format your answerarrow_forward
- I am confused on how to find the enthalpy change with this information. Thank you!arrow_forwardPlease answer both questionsarrow_forwardConsider these reactions, where M represents a generic metal. 1. 2 M(s) + 6 HCI(aq) 2 MCI, (аq) + 3 Н, (2) AH1 = -556.0 kJ 2. HCl(g) HCl(aq) AĦ2 = -74.8 kJ 3. H, (g) + Cl, (g) → 2 HCI(g) ΔΗ = -1845.0 kJ 4. MCI, (s) – MCI, (aq) AĦ4 = -493.0 kJ Use the given information to determine the enthalpy of the reaction 2 M(s) + 3 Cl, (g) – - 2 MCl, (s) -556.0 ΔΗ- Incorrectarrow_forward
- A chemist measures the enthalpy change AH during the following reaction: Fe(s) + 2 HCl(g)→FECL,(s) + H,(9) AH=-157, kJ Use this information to complete the table below. Round each of your answers to the nearest kJ/mol. reaction ΔΗ x10 을Fels) + 3 1 1 1 -HCI(g) FeCl, (s) + 3 (8) | kJ 3 FeCl, (6) + (8) Fe(s) + HCI(g) 6 3 FeCl, (s) + H, (g) Fe(s) + 2HC1(g)arrow_forwardIf a system has 225 kcal of work done to it, and releases 5.00 x 10² kJ of heat into its surroundings, what is the change in internal energy (AE or AU) of the system? ΔΕ= kJarrow_forwardA chemist measures the enthalpy change AH during the following reaction: Sg(s) + 24 F,(g)→8 SF(g) AH=-9672. kJ Use this information to complete the table below. Round each of your answers to the nearest kJ/mol. reaction ΔΗ 10 SSF, (3) → S, (3) + 24F, (z) S,6) + 6F, (g) 2SF, (3) 4 4 SF, (e) -- S,(1) + 4F, (3)arrow_forward
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