Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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DISACCHARIDE
The condensation of two monosaccharide forms a disaccharide or polysaccharide if several
monosaccharides are involved. When monosaccharides join together one water molecule is produced.
Usually the C-1 OH and C-4 OH or C-1 OH and C-6 OH are involved in the formation of new bond
called the glycosidic bond (an ether linkage). Two possible glycosidic bonds are the 1,4’-alpha
glycosidic bond and 1,4’-beta glycosidic bond. Did you notice the difference between the two glycosidic
bonds?
1,4'-alpha glycosidic bond
ÇH2OH
ÇH2OH
Он
H.
H
OH is lost
-H2O
H
H
он
CH2OH
Он
Но
OH
Но
+
ÇH2OH
H
OH
ОН
alpha anomer
он
H
H
OH
Он
H
OH
H is lost>HỌ
OH
1,4'-alpha glycosidic bond
OH
alpha anomer
1,4'-beta glycosidic bond
beta anomer
CH2OH
OH
ÇH2OH
H is removed
H
Он
О он
CH2OH
НО
CH2OH
OH
H
-O OH
H
OH
H
H
H2O
H
OH
OH
OH
но
H
OH is removed
Но
H
OH
OH
1,4'-beta glycosidic bond
beta anomer
-오
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Transcribed Image Text:DISACCHARIDE The condensation of two monosaccharide forms a disaccharide or polysaccharide if several monosaccharides are involved. When monosaccharides join together one water molecule is produced. Usually the C-1 OH and C-4 OH or C-1 OH and C-6 OH are involved in the formation of new bond called the glycosidic bond (an ether linkage). Two possible glycosidic bonds are the 1,4’-alpha glycosidic bond and 1,4’-beta glycosidic bond. Did you notice the difference between the two glycosidic bonds? 1,4'-alpha glycosidic bond ÇH2OH ÇH2OH Он H. H OH is lost -H2O H H он CH2OH Он Но OH Но + ÇH2OH H OH ОН alpha anomer он H H OH Он H OH H is lost>HỌ OH 1,4'-alpha glycosidic bond OH alpha anomer 1,4'-beta glycosidic bond beta anomer CH2OH OH ÇH2OH H is removed H Он О он CH2OH НО CH2OH OH H -O OH H OH H H H2O H OH OH OH но H OH is removed Но H OH OH 1,4'-beta glycosidic bond beta anomer -오
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