Determine the standard enthalpy change and std. Gibbs free energy change of reaction at 400 k for the reaction CO(g) +2H2(g) → CH3OH (g) At 298.15 K, ∆Hf,CO (g) 0 = -26.41 kcal/mol, ∆Hf,CH3OH(g) 0 = -48.08 kcal/mol, ∆Gf,CO (g) 0 = -32.8079 kcal/mol, ∆Gf,CH3OH(g) 0 = -38.69 kcal/mol, The standard heat capacity of various components is given by, Cp 0 = a + bT + cT 2 + dT 3 , where Cp 0 is in cal/mol-K and T is in K Component a b ×102 c ×105 d ×109 CH3OH 4.55 2.186 -0.291 -1.92 CO 6.726 0.04 0.1283 -0.5307 H2 6.952 -0.0457 0.09563 -0.2079
Determine the standard enthalpy change and std. Gibbs free energy change of reaction at 400 k for the reaction CO(g) +2H2(g) → CH3OH (g) At 298.15 K, ∆Hf,CO (g) 0 = -26.41 kcal/mol, ∆Hf,CH3OH(g) 0 = -48.08 kcal/mol, ∆Gf,CO (g) 0 = -32.8079 kcal/mol, ∆Gf,CH3OH(g) 0 = -38.69 kcal/mol, The standard heat capacity of various components is given by, Cp 0 = a + bT + cT 2 + dT 3 , where Cp 0 is in cal/mol-K and T is in K Component a b ×102 c ×105 d ×109 CH3OH 4.55 2.186 -0.291 -1.92 CO 6.726 0.04 0.1283 -0.5307 H2 6.952 -0.0457 0.09563 -0.2079
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter17: Chemcial Thermodynamics
Section: Chapter Questions
Problem 17.107QE: Calculate the standard Gibbs free-energy change when SO3 forms from SO2 and O2 at 298 K. Why is...
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Determine the standard enthalpy change and std. Gibbs free energy change of
reaction at 400 k for the reaction
CO(g) +2H2(g) → CH3OH (g)
At 298.15 K, ∆Hf,CO (g)
0 = -26.41 kcal/mol, ∆Hf,CH3OH(g)
0 = -48.08 kcal/mol,
∆Gf,CO (g)
0 = -32.8079 kcal/mol, ∆Gf,CH3OH(g)
0 = -38.69 kcal/mol,
The standard heat capacity of various components is given by,
Cp
0 = a + bT + cT
2 + dT
3
, where Cp
0
is in cal/mol-K and T is in K
Component a b ×102 c ×105 d ×109
CH3OH 4.55 2.186 -0.291 -1.92
CO 6.726 0.04 0.1283 -0.5307
H2 6.952 -0.0457 0.09563 -0.2079
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