Answered: . Is the Boudouard Reaction exothermic…

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

ChapterA1: Evaluation Of Analytical Data

Section: Chapter Questions

Problem A1.3QAP

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1. Is the Boudouard Reaction exothermic or endothermic?

2. Is the reaction spontaneous at low temperatures?

3. Is the reaction spontaneous at high temperatures?

4. At what temperature the reaction becomes spontaneous?

5. The vant Hoff's equation works if there is no (or very weak) temperature dependence of change of standard enthalpy and standard entropy on temperature. Does your vant Hoff's graph support this assumption?

InK vs 1/T
1.000E+01
5.000E+00
0.000E+00
5.000E-047.000E-04.000E-04.100E-03.300E-03.500E-01.700E-03.900E-03
-5.000E+00
-1.000E+01
y =-20627x + 21.11
R2 = 0.9999
-1.500E+01
-2.000E+01
-2.500E+01
1/T, K
Graph 8. InK vs 1/T (Vant Hoff's equation)
InK

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