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- Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.Show that any two of the irreducible representations of the following point groups are orthogonal to each other. a C2 b C2v c D2h d Oh e TdStructural isomers can have very different point groups. There are three isomers of dichlorobenzene. Identify the point groups of the three isomers.
- Determine the point groups for H -C = C - CH3.Consider the octahedral species CrCl63- (point group Oh). What point group results by removing one Cl replacing one Cl with one Br removing two trans Cl’s removing two cis Cl’s removing three mutually adjacent Cl’s.Determine the point groups for H -C = C - F.
- Consider the octahedral species CrCl63- (point group Oh). What point group results by (d) removing two cis Cl’s (e) removing three mutually adjacent Cl’s.Identify the point groups to which the following objects belong: (i) a sphere, (ii) an isosceles triangle, (iii) an equilateral triangle, (iv) an unsharpened cylindrical pencil.Consider the octahedral species CrCl63- (point group Oh). What point group results by (a) removing one Cl (b) replacing one Cl with one Br (c) removing two trans Cl’s