Describe the bonding in the methanol molecule, CH30H, using valence bond theory.

Chemistry: An Atoms First Approach
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Chapter4: Molecular Structure And Orbitals
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Problem 5RQ: What hybridization is required for central atoms that have a tetrahedral arrangement of electron...
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Describe the bonding in the methanol
molecule, CH30H, using valence bond
theory.
O A. The electron-pair geometry around
both the C and O atoms in CH3OH is
tetrahedral.
Thus, we assign sp2 hybridization to each
atom, and the C – O bond is formed
by overlap of sp² orbitals on these atoms.
Each C - H bond is formed by overlap of
a carbon
sp³ orbital with a hydrogen 1s orbital, and
the 0 - H bond is formed by overlap of an
oxygen
sp3 orbital with the hydrogen 1s orbital.
Two lone pairs on oxygen occupy the
remaining
sp3 orbitals on the atom.
O B. The electron-pair geometry around
both the C and O atoms in CH3OH is
tetrahedral.
Thus, we assign sp³ hybridization to each
atom, and the C - O bond is formed by
overlap of sp3 orbitals on these atoms.
Each C - H bond is formed by overlap of
a carbon
sp? orbital with a hydrogen 1s orbital, and
the 0 - H bond is formed by overlap of an
oxygen
sp? orbital with the hydrogen 1s orbital.
Two lone pairs on oxygen occupy the
remaining
sp2 orbitals on the atom.
O C. The electron-pair geometry around
both the C and O atoms in CH3OH is
square planar.
Thus, we assign sp³ hybridization to each
atom, and the C – O bond is formed by
overlap of sp3 orbitals on these atoms.
Each C - H bond is formed by overlap of
a carbon
Transcribed Image Text:Describe the bonding in the methanol molecule, CH30H, using valence bond theory. O A. The electron-pair geometry around both the C and O atoms in CH3OH is tetrahedral. Thus, we assign sp2 hybridization to each atom, and the C – O bond is formed by overlap of sp² orbitals on these atoms. Each C - H bond is formed by overlap of a carbon sp³ orbital with a hydrogen 1s orbital, and the 0 - H bond is formed by overlap of an oxygen sp3 orbital with the hydrogen 1s orbital. Two lone pairs on oxygen occupy the remaining sp3 orbitals on the atom. O B. The electron-pair geometry around both the C and O atoms in CH3OH is tetrahedral. Thus, we assign sp³ hybridization to each atom, and the C - O bond is formed by overlap of sp3 orbitals on these atoms. Each C - H bond is formed by overlap of a carbon sp? orbital with a hydrogen 1s orbital, and the 0 - H bond is formed by overlap of an oxygen sp? orbital with the hydrogen 1s orbital. Two lone pairs on oxygen occupy the remaining sp2 orbitals on the atom. O C. The electron-pair geometry around both the C and O atoms in CH3OH is square planar. Thus, we assign sp³ hybridization to each atom, and the C – O bond is formed by overlap of sp3 orbitals on these atoms. Each C - H bond is formed by overlap of a carbon
square planar.
Thus, we assign sp° hybridization to each
O bond is formed by
atom, and the C -
overlap of sp³ orbitals on these atoms.
Each C - H bond is formed by overlap of
a carbon
sp³ orbital with a hydrogen 1s orbital, and
the o - H bond is formed by overlap of an
охудen
sp³ orbital with the hydrogen 1s orbital.
Two lone pairs on oxygen occupy the
remaining
sp³ orbitals on the atom.
D. The electron-pair geometry around
both the C and O atoms in CH3OH is
tetrahedral.
Thus, we assign sp³ hybridization to each
atom, and the C - O bond is formed
by overlap of sp orbitals on these atoms.
Each C - H bond is formed by overlap of
a carbonsp³ orbital with a hydrogen 1s
orbital, and the 0 - H bond is formed by
overlap of an oxygensp³ orbital with the
hydrogen 1s orbital. Two lone pairs on
oxygen occupy the remaining
sp3 orbitals on the atom.
Transcribed Image Text:square planar. Thus, we assign sp° hybridization to each O bond is formed by atom, and the C - overlap of sp³ orbitals on these atoms. Each C - H bond is formed by overlap of a carbon sp³ orbital with a hydrogen 1s orbital, and the o - H bond is formed by overlap of an охудen sp³ orbital with the hydrogen 1s orbital. Two lone pairs on oxygen occupy the remaining sp³ orbitals on the atom. D. The electron-pair geometry around both the C and O atoms in CH3OH is tetrahedral. Thus, we assign sp³ hybridization to each atom, and the C - O bond is formed by overlap of sp orbitals on these atoms. Each C - H bond is formed by overlap of a carbonsp³ orbital with a hydrogen 1s orbital, and the 0 - H bond is formed by overlap of an oxygensp³ orbital with the hydrogen 1s orbital. Two lone pairs on oxygen occupy the remaining sp3 orbitals on the atom.
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