Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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if we calculate total differential of P as a function of Temperature and Volume with respect to isothermal compressibility factor and co-efficient of thermal expansion, then the value comes out to be
c1T+c1T/V + c2T2/2
if we neglect c1T, then the given expression comes out. But we can not neglect it without any external condition. The complete solution is given in the next step.
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