Cyclopropane isomerizes into propene when heated to 500°C in the gas phase. The extent of conversion was followed by gas chromatography by allowing the reaction to proceed for a time with various initial pressures: Po/Torr t/s 200 200 400 400 600 600 100 200 100 200 100 200 pr 186 173 373 347 559 520 where p, is the initial pressure of cyclopropane and pr the pressure of cyclopropane after t seconds. What is the order of the reaction and the value of the rate constant for the reaction under these conditions? (NOTE: px (nx/V)*RT = [X]*RT, so you can use pressure-rather than concentration-in the rate law equations.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Cyclopropane isomerizes into propene when heated to 500°C in the gas phase. The extent of conversion
was followed by gas chromatography by allowing the reaction to proceed for a time with various initial
pressures:
Po/Torr
t/s
200
200
400
400
600
600
100
200
100
200
100
200
Pr
186
173
373
347
559
520
where
is the order of the reaction and the value of the rate constant for the reaction under these conditions?
(NOTE: px = (nxV)*RT = [X]*RT, so you can use pressure-rather than concentration-in the rate law equations.)
P.
is the initial pressure of cyclopropane and p, the pressure of cyclopropane after t seconds. What
Transcribed Image Text:Cyclopropane isomerizes into propene when heated to 500°C in the gas phase. The extent of conversion was followed by gas chromatography by allowing the reaction to proceed for a time with various initial pressures: Po/Torr t/s 200 200 400 400 600 600 100 200 100 200 100 200 Pr 186 173 373 347 559 520 where is the order of the reaction and the value of the rate constant for the reaction under these conditions? (NOTE: px = (nxV)*RT = [X]*RT, so you can use pressure-rather than concentration-in the rate law equations.) P. is the initial pressure of cyclopropane and p, the pressure of cyclopropane after t seconds. What
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Quality Assurance and Calibration Methods
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY