Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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- 12.105 Using the kinetic-molecular theory, explain why an increase in pressure produces more N2O4 in the following system: N2O4(g)2NO2(g)arrow_forwardXenon and fluorine will react to form binary compounds when a mixture of these two gases is heated to 400C in a nickel reaction vessel. A 100.0-mL nickel container is filled with xenon and fluorine, giving partial pressures of 1.24 atm and 10.10 atm, respectively, at a temperature of 25C. The reaction vessel is heated to 400C to cause a reaction to occur and then cooled to a temperature at which F2 is a gas and the xenon fluoride compound produced is a nonvolatile solid. The remaining F2 gas is transferred to another 100.0-mL nickel container, where the pressure of F2 at 25C is 7.62 atm. Assuming all of the xenon has reacted, what is the formula of the product?arrow_forwardAs weather balloons rise from the earths surface, the pressure of the atmosphere becomes less, tending to cause the volume of the balloons to expand. However, the temperatura is much lower in the upper atmosphere than at sea level. Would this temperatura effect tend to make such a balloon expand or contract? Weather balloons do, in fact, expand as they rise. What does this tell you?arrow_forward
- A typical barometric pressure in Redding. California, is about 750 mm Hg. Calculate this pressure in atm and kPa.arrow_forward105 The decomposition of mercury(II) thiocyanate produces an odd brown snake-like mass that is so unusual the process was once used in fireworks displays. There are actually several reactions that take place when the solid Hg(SCN)2 is ignited: 2Hg(SCN)2(s)2HgS(s)+CS2(s)+C3N4(s)CS2(s)+3O2(g)CO2(g)+2SO2(g)2C3N4(s)3(CN)2(g)+N2(g)HgS(s)+O2(g)Hg(l)+SO2(g) A 42.4-g sample of Hg(SCN)2 is placed into a 2.4-L vessel at 21°C. The vessel also contains air at a pressure of 758 torr. The container is sealed and the mixture is ignited, causing the reaction sequence above to occur. Once the reaction is complete, the container is cooled back to the original temperature of 21°C. (a) Without doing numerical calculations, predict whether the final pressure in the vessel will be greater than, less than, or equal to the initial pressure. Explain your answer. (b) Calculate the final pressure and compare your result with your prediction. (Assume that the mole fraction of O2 in air is 0.21.)arrow_forward93 The complete combustion of octane can be used as a model for the burning of gasoline: 2C8H18+25O216CO2+18H2O Assuming that this equation provides a reasonable model of the actual combustion process, what volume of air at 1.0 atm and 25°C must be taken into an engine to burn 1 gallon of gasoline? (The partial pressure of oxygen in air is 0.21 atm and the density of liquid octane is 0.70 g/mL.)arrow_forward
- A cylinder of compressed gas is labeled Composition (mole %): 4.5% H2S, 3.0% CO2, balance N2. The pressure gauge attached to the cylinder reads 46 atm. Calculate the partial pressure of each gas, in atmospheres, in the cylinder.arrow_forwardThe graph below is similar to that of Figure 12.2. If after 100 s have elapsed the partial pressure of N2O4 is increased to 1.0 atm, what will the graph for N2O4 look like beyond 100 s?arrow_forward
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