Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Consider the [VII(H2O)6]2+ ion.
Explain why there are this number of bands and not more or less, which might be expected (i.e., which sets of electronic transitions give rise to these bands).
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- has a crystal field splitting energy, o, of 2.60102 kJ/mol. What is the wavelength responsible for this energy?arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forwardDraw the octahedral crystal field d orbital splitting diagrams for [Fe(OH2)6] 2+ and [Fe(CN)6] 3. Indicate if the diagrams are high spin and low spin. give the names of the d-orbitals (dxz, dxy, dzy, dz2, dx2 - y2) label the appropriate orbital sets eg* and t2g and show how the electrons populate the diagram. (Hint: Pairing energy for 3d orbitals Fe 2+ = 29875 cm-1, Fe 3+ = 19150 cm-1; delta OH for Fe(OH2)6]2+ = 14300 cm-1 and delta OH for [Fe(CN)6]3 - is 35000 cm-1arrow_forward
- 5. In the absence of the ethylenediamine ligands, the hexa reacts rapidly with water according to the following scheme. [Co(H2O)6]3+ + H2O→ [Co(H2 O)6}²+ + O2 + H* Balance the equation and determine which species is the reducing agent.arrow_forwardThe cobalt carbonyl complex, Co2(CO)8, undergoes an oxidation with hydrogen gas to form a monomeric metal hydride product, HCo(CO)4. The resulting complex could have one of three possible structures, so an infrared spectrum was obtained. If the spectrum has 12 observable bands overall, what is the likely structure?arrow_forwardHow many sigma bonds are present in [Ti(H2O)6]³+?arrow_forward
- Which is more acidic and why? [Fe(H2O)6]2+ or [Fe(NH3)(H2O)5]2+arrow_forwardDraw the d orbital electronic configuration of [Cr(co)6]3+ how many unpaired electrons are present if six Br- groups were substituted for the six co groups to give [Cr(Br)6]3+ Would you expect CFSE to increase or decrease and whyarrow_forward1.What are the molybdenum oxidation states , ground d-electron configurations and ground electronic spectroscopic states of Mo(CO)6 and Mo(OCH3)6 ? 2.Describe how the Mo-C π bonding in Mo(CO)6 is enhanced by the synergism with the Mo-CO sigma bonding interaction .arrow_forward
- The self exchange electron-transfer reaction between [Co(en)3]3+ and [Co(en)3]2+ is rather slow. Explain this observation on the basis of d-orbital occupations.arrow_forward3. Consider the blue-colored compound, [Cr(H₂O)]3³ and the yellow-colored compound, [Cr(CN)6]³. Calculate their magnetic moments and discuss their magnetic properties and their color.arrow_forwardHow many unpaired electrons do you predict for the tetrahedral[MnCl4]2 - ion?(a) 1, (b) 2, (c) 3, (d) 4, (e) 5.arrow_forward
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