Consider the reaction: NO2 + O3 -> NO3 + O2 Experiment [NO2], M [O3], M Rate, M/s Trial 1 0.21 0.70 6.30x10-3 Trial 2 0.63 0.65 1.89x10-2 Trial 3 0.21 0.35 3.15x10-3 Trial 4 0.42 0.35 6.30x10-3 A) Which experimental trial expressed the rate order of NO2? B) Which experimental trial expressed the rate order of O3? C) What is the rate order of O3? D) What is the rate order of NO2? E) What is the overall rate reaction?

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Consider the reaction:

NO2 + O-> NO+ O2

Experiment [NO2], M [O3], M Rate, M/s
Trial 1 0.21 0.70 6.30x10-3
Trial 2 0.63 0.65 1.89x10-2
Trial 3 0.21 0.35 3.15x10-3
Trial 4 0.42 0.35 6.30x10-3

A) Which experimental trial expressed the rate order of NO2?

B) Which experimental trial expressed the rate order of O3?

C) What is the rate order of O3?

D) What is the rate order of NO2?

E) What is the overall rate reaction?

D) What is the rate constant (M-1s-1) of the reaction?

F) Calculate the rate of [NO3] production at 0.84 M [NO3] and 1.4 M [O3]

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