Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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6. Consider the reaction 2NO(g) + O2(g) → 2NO2 (g). If Kp=2.2x1012 at T= 25.0 °C. What is Kp at T= 50.0 °C?
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- For the following reaction, Kp = 0.113 at 25°C, and the standard free energy change is 5.4 kJ/mol. If Todd does an experiment where the initial pressures are PN2040.453 atm and PNO2 = 0.122 atm, what are the correct units of the free energy change of the reaction? N2O4(g) 2 NO2(g)arrow_forwardAt 13.7 °C the concentration equilibrium constant K = 2.0 × 10 for a certain reaction. Here are some facts about the reaction: • C The constant pressure molar heat capacity C₁ = 2.49 J-mol K. •If the reaction is run at constant pressure, 147. kJ/mol of heat are released. •If the reaction is run at constant pressure, the volume increases by 13.%. ○ Yes. Using these facts, can you calculate K, at 3.8 °C? x10 No. If you said yes, then enter your answer at right. Round it to 2 significant digits. n If you said no, can you at least decide whether Kat 3.8 °C will be bigger or smaller than K at -13.7 °C? Yes, and K will be bigger. Yes, and K will be smaller. No. xarrow_forwardConsider the following equilibrium: 2NOC1 (g) 2NO(g) + Cl₂ (g) AG=41. KJ Now suppose a reaction vessel is filled with 3.76 atm of nitrosyl chloride (NOC1) and 6.26 atm of nitrogen monoxide (NO) at 1161. °C. Answer the following questions about this system: Under these conditions, will the pressure of NO tend to rise or fall? Is it possible to reverse this tendency by adding C1₂? In other words, if you said the pressure of NO will tend to rise, can that be changed to a tendency to fall by adding C1₂? Similarly, if you said the pressure of NO will tend to fall, can that be changed to a tendency to rise by adding Cl₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of C12 needed to reverse it. Round your answer to 2 significant digits. OO rise fall yes no atm x10 X Śarrow_forward
- Consider the following equilibrium: 2NOC1 (g) → 2NO(g) + Cl₂ (g) AG = 41. kJ Now suppose a reaction vessel is filled with 8.30 atm of nitrosyl chloride (NOC1) and 5.80 atm of chlorine (C1₂) at 878. °C. Answer the following questions about this system: Under these conditions, will the pressure of Cl₂ tend to rise or fall? Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of Cl₂ will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of Cl₂ will tend to fall, can that be changed to a tendency to rise by adding NO? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. оо rise fall yes no 0 atm x10 X Śarrow_forwardConsider the reactions and their respective equilbrium constants: NO(g) + 1/2BR(g) > NOBR(g) KP = 5.3 2NO(g) > N2(g) + O2(g) KP = 2.1 x 1030 Use these reactions and their equilbrium constants to predict the equlibrium constant for the following reaction: N2(g) + O2(g) + Br2(g) > 2NOBR(g)arrow_forwardYou are given the following: H2 (g) + Br2 (g) 2 HBr (g) Kp = 7.9 x 1011 H2 (g) 2 H (g) Kp = 4.8 x 10-41 Br2 (g) 2 Br (g) Kp = 2.2 x 10-15 What is Kp for the reaction shown below? H (g) + Br (g) HBr (g) Kp = ?arrow_forward
- At 487 K, this reaction has a Ke value of 0.0463. 2 X(g) + 3 Y(g) = 2Z(g) Calculate Kp at 487 K. Note that the pressure is in units of atmosphere (atm). Kp =arrow_forward8. Consider the equilibrium reaction: N2(g) + O2(g) = 2 NO(g) Kp 4.10 x 10³ at 2000°C a) If 1.00 atm of nitrogen gas and 1.00 atm of oxygen gas is mixed with 0.10 atm of nitrogen monoxide in a 500.0 mL container at 2000°C, in which direction will the reaction proceed to reach equilibrium? Show all work to justify your answer. b) What is the concentration of each gas when equilibrium is reached at 2000°C? Show all your work. Equilibrium Partial Pressures: PN₂ = Po₂ = 1.02 atm and PNO = 0.07 atm Use PV = nRT Answer: Equilibrium Concentrations: [N₂] = [0₂] = 5.47 x 10-3 mol/L and [NO] = 4 x 10+ Marrow_forwardThe equilibrium constant, Kp, for the following reaction is 1.57 at 600 K.CO(g) + Cl2(g) COCl2(g)If ΔH° for this reaction is -108 kJ, what is the value of Kp at 699 K?Kp =arrow_forward
- 2. Use the following information to calculate Kp and Ke for each reaction at 1000 K. CO2(g) + C(s) = 2C0(g) Kp = 1.50 at 1000 K a. 2c0(g) = CcO2(g) + C(s) 1 b. ½ CO2(g) + ½ C(s) = CO(g) c. 4C0(g) = 2CO2(g) + 2C(s)arrow_forwardConsider the following equilibrium: 2NH3(g) → N₂(g) + 3H₂(g) AG = 34. kJ Now suppose a reaction vessel is filled with 6.39 atm of ammonia (NH3) and 0.200 atm of hydrogen (H₂) at 206. °C. Answer the following questions about this system: Under these conditions, will the pressure of NH3 tend to rise or fall? Is it possible to reverse this tendency by adding N₂? In other words, if you said the pressure of NH3 will tend to rise, can that be changed to a tendency to fall by adding N₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding N₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of N₂ needed to reverse it. Round your answer to 2 significant digits. OO U rise fall yes no atm x10 X Śarrow_forward
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