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- Which of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substanceFrom the following data determined at 298 K, determine (a) A, H and A₁U for reaction (4) at 298 K; (b) AfH for HI(g) and H₂O(g) at 298 K. Assume ideal gas behavior when necessary. (1) H₂(g) + I2(g) → 2 HI(g) (2) 2H₂(g) + O₂(g) → 2H₂O (g) (3) 1₂ (s)→ I2(g) (4) 4HI(g) + O₂(g) → 21₂(g) + 2H₂O(g) ΔΗΘ = +52.96 kJ mol-¹ A₂H = -483.64 kJ mol-1 A₂H = +62.44 kJ mol-¹From the following data, determine A;H© for diborane, B2H6(g), at 298 K: (1) B,H(g) + 3 O2(g)→ B2O3(s) + 3 H2O(g) A,H© =-1941 kJ mol (2) 2 B(s) + 3/2 O2(g)→ B2O3(S) A,H© =-2368 kJ mol· (3) H2(g) + 1/2 O2(g) → H2O(g) A„H© = -241.8 kJ mol-
- (a) Under what conditions is a dA < 0 condition thatdefines the spontaneity of a process?(b) A sample containing 2.50 moles of He (1 bar, 350. K) ismixed with 1.75 mol of Ne (1 bar, 350. K) and 1.50 mol ofAr (1 bar, 350. K). Calculate AGmixing and ASmixing.6) Calculate the final temperature of a sample of carbon dioxide of mass 16.0 g that is expanded reversibly and adiabatically from 500 cm³ at 298.15 K to 2.00 dm³.Calculate ArxnG for the following reaction at 375 K. Assume that Arxn is constant over the temperature range given. SO2(g) + O2(g) SO3(g) Values of A, Gº and AƒÃ¤ in kJ mol¹¹ at 298 K are given below: Af Gº Af He SO3(g) -371.06 -395.72 SO2(g) -300.19 -296.83 O2(g) 0 0
- The following reaction has these standard thermodynamie parameters: An-30.6 kmol and AS 55.3 J(mol K).(5) Use the graph below, schematically describing the change in Gibbs free energy for a chemical reaction as a function of the reaction progress, to answer the following questions: A B Reaction Progress (i) Which of the following inequalities correctly describes point A? (Q is the reaction quotient, and A,G is the Gibbs reaction energy.) a. A,G = 0, Q > 1, [Products] > [Reactants] b. A,G > 0, Q = 1, [Products] = [Reactants] c. A,G 1, [Products] < [Reactants] (ii) What state of the system is represented by point B? (iii) Indicate the sign of A,G, at points A, B and C. Gibbs Free EnergyChose the correct option that represents the change in Gibbs free er (A) dG =µdn, (B) dG =Eµn, (C) dG =-Eudn (D) dG =µ dn,
- Using values from Appendix C of your textbook, calculate the value of Keq at 298 K for each of the following reactions: (a) 6 C(graphite) + 6 H₂O(1) C6H1206(5) Keq=1.1E- (b) 2 NO(g) + Cl₂(g) = 2 NOCI(g) Kea (c) 2 N₂Ha(g) + 2 H₂O(1) = 4 NHy(9) + O₂(g) KeaGiven the following reaction at 298 K: 2 H2S(g) + SO2(9) → Ss(s) + 2 H20(g) Part A ArG" = -102 kJ mol Determine the value of the reaction quotient Q when: Pu,s = 2.00 bar; Pso, = 0.185 bar; and Pa,0 = 1.245 ba Express your answer using three significant figures. fe kevboard shortcuts help Temgrates Symbols undo rego Q =For the reaction Cr(C6H6)2 (s) --> Cr(s) + 2 C6H6 (g), the reaction internal energy change at 1 atm and 538 K is DUrxno(T = 538K) = 8.0 kJ/mol. (a) Estimate the molar enthalpy of reaction at 1 atm and 538 K for the above reaction. (b) If the standard molar enthalpy of formation for C6H6 at 1 atm and 538 K is about DHfo (C6H6 (g)) = 84 kJ/mol, estimate the standard enthalpy of formation of Cr(C6H6)2 (s) at 1 atm and 538 K.