Consider the following cell: |Zn (s) | Ca2* (aq) , so3²" (aq) || Hg2+ (aq) , F° (aq) | Pt (s) | a) Indicate the Oxidizing Agent b) Indicate the Reducing Agent c) Write the half reactions that occurs at the cathode d) Write the half reactions that occurs at the anode e) Write the overall net cell reaction f) Calculate the cell potential g) Indicate if electricity is produced or consumed by the cell h) Indicate if the cell is galvanic or electrolytic

MnO4– + Sn ----> MnO2 + Sn2+ A) Identify the half-reaction that occurs at the cathode. B) Identify the oxidizing agent and anode. C) standard cell potential? D) What will be the potential of a cell constructed using 57.0 g MnO2, 1.57 M MnO4–, 14.8 g Pt, 12.5 g Sn and 0.87 M Sn2+ at pH 2.5?

Consider the following voltaic cellat 25°C: Al(s) | Al3*(0.20 M, aq) || Al3+(0.75 M, aq) | Al(s) If the standard reduction potential for the Al3+(aq) /Al(s) redox couple is -1.66 V, what is the overall cell reaction and the cell potential of the voltaic cell shown above? (Reference the cell as written above.) The overall cell reaction is Al3+(0.75 M, aq) AIS*(0.20 M, ag) and E°cell = +0.0113 V. There is no overall cell reaction and E°cell = 0.00 V. The overall cell reaction is Al3+(0.20 M, aq) Als*(0.75 M, aq) and E°cell = +0.0113 V. The overall cell reaction is Al3+(0.20 M, aq) →A13+(0.75 M, ag) and E°cell| = -0.0113 V. The overall cell reaction is Al3*(0.75 M, aq) →AI3*(0.20 M, aq) and E°cell = -0.0113 V. None of these

CuSO4(aq) + 2Ag(s) Ag2SO4(aq) + Cu(s) write out the oxidation half reaction and identify which chemical -a) species is oxidized b) species is reduced write out the reduction half reaction and identify which chemical c) Calculate the cell potential for a galvanic cell with this reaction. Predict whether the reaction will proceed spontaneously.

Consider the electrolysis reactions cathode anode whose standard reduction potentials can be found in this table. Calculate the voltage needed to drive the net reaction if the current is negligible. Ecell = Cu²+ (aq, 0.177 M) +2e=Cu(s) H₂O(1) ⇒ 10₂(g, 1 bar) + 2 H+ (aq, 0.195 M) + 2 e¯ The cell has a resistance of 66.0 and a current of 7.17 mA when the cathode overpotential is 0.231 V and the anode overpotential is 0.050 V. Calculate the voltage needed to overcome these effects and drive the net reaction. Ecell = V V

3) Draw a picture of the galvanic cell represented by the line notation below and then write the reduction half-reactions for each electrode. Also identify the anode and cathode for each half cell. Pt (s) | Fe3+ (aq), Fe2+ (aq) || Cr2O72-(aq), Cr3+ (aq), HA (aq) | Pt (s)