Consider a reaction with a large negative Gibbs energy change, as shown below: YZ, AG/ - 42.6 kJ mol The reaction is initiated by adding 16 mmol of compound Y into the flask, in the absence of compound Z is present. After 48 hours, analysis reveals the presence of 4 mmol of Z and 12 mmol of Y. Which is the most likely explanation? Y and Z have reached equilibrium concentrations. An enzyme has shifted the equilibrium toward Y. Formation of Z is kinetically slow; equilibrium has not been reached by 48 hours. Formation of Z is thermodynamically unfavorable. OTwo of the above explanations are reasonable.
Consider a reaction with a large negative Gibbs energy change, as shown below: YZ, AG/ - 42.6 kJ mol The reaction is initiated by adding 16 mmol of compound Y into the flask, in the absence of compound Z is present. After 48 hours, analysis reveals the presence of 4 mmol of Z and 12 mmol of Y. Which is the most likely explanation? Y and Z have reached equilibrium concentrations. An enzyme has shifted the equilibrium toward Y. Formation of Z is kinetically slow; equilibrium has not been reached by 48 hours. Formation of Z is thermodynamically unfavorable. OTwo of the above explanations are reasonable.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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