CONCEPT CHECK No. 2 (Continued): Fill in the blank spaces with your answers for Questions 1 & 2 for the designated (R) & (S) configurations. Follow instructions on the choices given below. Concept Check: Configurational Isomers? (1) Tell whether the two structures in each pair represent enantiomers or two molecules of the same compound in different orientations. Designate each chirality center as (R) or (S). CH, H OH and CH (2) Consider the following pairs of structures. Designate each chirality center as (R) or (S ) and identify the relationship between them by describing them as representing enantiomers, diastereomers, constitutional isemers, or two melecules of the same compound. la) Ha and nd Br CH (b) and (d) and Br a Cnaa WRITE: SS - if both structures have an S chirality center SR - if the first structure given has an S chirality center & the second has R RR - if both structures have an R chirality center RS - if the first structure given has an R chirality center & the second has S XS - if the first structure given is achiral & the second has an S configuration

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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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CONCEPT CHECK No. 2 (Continued): Fill in
the blank spaces with your answers for
Questions 1 & 2 for the designated (R) & (S)
configurations. Follow instructions on the
choices given below.
Concept Check: Configurational Isomers?
(1) Tell whether the two structures in each pair represent enantiomers or two molecules of the same
compound in different orientations. Designate each chirality center as (R) or (S).
CH,
H OH
and
CH,
(2) Consider the following pairs of structures. Designate each chirality center as (R) or (S ) and identify
the relationship between them by describing them as representing enantiomers, diastereomers,
constitutional isomers, or two molecules of the same compound.
H OH
la) Ha
and
nd
Br
CH
CH,
H. CH,
(b)
(d)
and
nd
aCnayam
WRITE:
SS - if both structures have an S
chirality center
SR - if the first structure given has an S
chirality center & the second has R
RR - if both structures have an R
chirality center
RS - if the first structure given has an R
chirality center & the second has S
XS - if the first structure given is achiral
& the second has an S configuration
XR - if the first structure given is achiral
& the second has R configuration
SX - if the first structure has an S
configuration and the second is achiral
RX - if the first structure has R
configuration and the second is achiral
XX - if both structures are achiral
Answers:
1. (a)
|
(b)
(c)
2. (a)
(b)
(c)
(d)
Transcribed Image Text:CONCEPT CHECK No. 2 (Continued): Fill in the blank spaces with your answers for Questions 1 & 2 for the designated (R) & (S) configurations. Follow instructions on the choices given below. Concept Check: Configurational Isomers? (1) Tell whether the two structures in each pair represent enantiomers or two molecules of the same compound in different orientations. Designate each chirality center as (R) or (S). CH, H OH and CH, (2) Consider the following pairs of structures. Designate each chirality center as (R) or (S ) and identify the relationship between them by describing them as representing enantiomers, diastereomers, constitutional isomers, or two molecules of the same compound. H OH la) Ha and nd Br CH CH, H. CH, (b) (d) and nd aCnayam WRITE: SS - if both structures have an S chirality center SR - if the first structure given has an S chirality center & the second has R RR - if both structures have an R chirality center RS - if the first structure given has an R chirality center & the second has S XS - if the first structure given is achiral & the second has an S configuration XR - if the first structure given is achiral & the second has R configuration SX - if the first structure has an S configuration and the second is achiral RX - if the first structure has R configuration and the second is achiral XX - if both structures are achiral Answers: 1. (a) | (b) (c) 2. (a) (b) (c) (d)
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