
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Choose the buffer with the greatest buffering capacity:
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d. 0.25M formic acid/formate buffer at pH 3, pKa 3.75 |
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b. 0.25M HEPESH+/HEPES buffer at pH 10, pKa = 8.08 |
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c. 0.75M acetic acid/acetate buffer at pH 4.76, pKa = 4.76 |
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a. 1M acetic acid/acetate buffer at pH 4.76, pKa = 4.76 |
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- 3arrow_forwardA buffer is prepared by mixing equal volumes of 0.075 M sodium acetate(NaC2H3CO2) of a 0.150 M acetic acid (H C2H3CO2, Ka = 1.8 10-5) solution. Write an equation for the reaction that occurs when a few drops ofhydrochloric acid are added to the buffer. Write an equation for the reaction that occurs when a few drops of sodiumhydroxide solution are added to the buffer.arrow_forwardFor a titration of 50.0 mL of 0.100 M acetic acid with 0.100 M NaOH, calculate pH: 1. at 0.00 mL NaOH addition (pH=2.87) 2. at 10.00 mL NaOH addition (pH=4.14) 3. at 25.00 mL NaOH addition (pH=4.74) 4. at 50.00 mL NaOH addition (pH=8.72) 5. at 51.00 mL NaOH addition (pH=11.00)arrow_forward
- Buffers will resist pH changes following the addition of acid or base within about +/-1 pH unit of the pka of a solution. True Falsearrow_forwardYou have 0.500 L of an 0.250 M acetate buffer solution (i.e. [HC2H3O2] + [C2H;O2] = 0.250 M) at pH 3.50. How many mL of 1.000 M NaOH must you add in order to change the pH to 5.37? Acetic acid has a pka of 4.74. mL 1 2 3 4 C 7 8 9. +/- х 100 +arrow_forwardYour goal is to make a buffer with a pH of 4.75 from acetic acid and sodium acetate. Assume the pKa for acetic acid is 4.74. What is the volume of 1 M sodium acetate added to make your buffer? Report your answer to the tenths place. To do this, we use the Henderson-Hasselbach Equation pH = pkA + log (base/acid) where pkA = 4.74 for acetic acid, pH = target pH and [base] /[acid] = x/(1-x) since we don't know the concentration of the base, we will call it x the acid is just 1-x, assuming the two add up to 100% solve for x, and then you know the mL of base and acid to add.arrow_forward
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