
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Acetic acid’s pKa is 4.75 and nitrous acid’s pKa is 3.16. If you made one buffer of equal parts acetic acid
and its conjugate base, then a second buffer of equal parts nitrous acid and its conjugate base, how
would the two buffers’ pHs compare to each other? Why? Note: no math is required to address this
question.
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- A student makes 100.0 mL of a 0.100 M solution of HNO2. What mass (in grams) of NaNO2 should the student add to the solution to make a buffer that buffers at a pH of 4.25. (Hint: use the Henderson-Hasselbalch equation to find the molarity, then find the number of moles required to achieve that concentration in 100.0 mL of solution.)arrow_forwardA beaker with 195 mLmL of an acetic acid buffer with a pH of 5.000 is sitting on a benchtop. The total molarity of acid and conjugate base in this buffer is 0.100 MM. A student adds 7.70 mLmL of a 0.440 MM HClHCl solution to the beaker. How much will the pH change? The pKapKa of acetic acid is 4.740. Express your answer numerically to two decimal places. Use a minus ( −− ) sign if the pH has decreased.arrow_forwardA buffer with pH of 4.74 is composed of 0.50mol sodium acetate and 0.60mol acetic acid is diluted to a volume of 1.0L. To increase its pH to 5.74, how many moles of sodium hydroxide should be added. 0.41 mol 0.25mol 0.55mol 0.50mol O 0.32molarrow_forward
- Buffers will resist pH changes following the addition of acid or base within about +/-1 pH unit of the pka of a solution. True Falsearrow_forwardWhich of the following is true about the titration curves of solutions of weak acids? A. The pH for optimal buffering power of a weak acid is 7.00. B. You can calculate the pKa of an acid, given the pH and the molar ratio of the acid and its conjugate base. C. The pKa of a weak acid is the pH at which the acid is completely dissociated. D. At a pH below the pKa of a weak acid, its conjugate base will predominate.arrow_forwardAcetic acid has a Ka of 1.8 x 10¬º. Three acetic acid/acetate buffer solutions, A, B, and C, were made using varying concentrations: A. [acetic acid] ten times greater than [acetate], B. [acetate] ten times greater than [acetic acid], and C. [acetate] = [acetic acid]. Match each buffer to the expected pH. Drag the appropriate items to their respective bins. • View Available Hint(s) Reset Help [acetate] ten times greater than [acetic acid] [acetate] = [acetic acid] [acetic acid] ten times greater than [acetate] pH = 3.74 pH = 4.74 pH = 5.74arrow_forward
- Cesium buffer helps in determining easily ionizable elements in ICP-MS and ICP-OES. But how? Cesium is easily ionizable element it produces more electrons in the plasma. In principle it should also suppress the ionization of metal of our interest. In that case Cesium buffers interferes our analysis. I don’t understand why Cesium helps to reduce the ionization of sodium and potassium, not the ionization of metal of our interest. Can you please explain how cesium helps to reduce the ionization of only a specific metal not the metal of interest?arrow_forwardWhy is the PH of the 0.1M acidic acid-sodium acetate buffer solution different from that 0.1M acetic acid?arrow_forwardUse the Henderson-Hasselbalch equation to calculate the pH of a buffer that is 0.18 M acetic acid and 0.85 M in acetate anion. The pKa value for acetic acid is 4.74. Round your answer to two decimal places.arrow_forward
- Compare the size of the change in pH value when HCl and NaOH are added to water vs. the size of the change in pH value for the standard reference buffer . Explain why the change for water vs. buffer was the same or different in size.arrow_forwardA buffer is made with 0.50 M weak acid and 0.50 M sodium salt of the conjugate base. The pKa of the weak acid is 9.30 After the addition of a small amount of strong concentrated acid, the new equilibrium concentrations are 0.6 M weak acid and 0.4 M base. Calculate the new pH. Enter result with 2 decimal places, digits only.arrow_forwardWhat is the relationship between the buffer range and the buffer-component concentration ratio?arrow_forward
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