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- Reaction of acetic acid, CH3CO2H, with isotopically labeled CH318OH and catalytic sulfuric acid gives: 180 A) CH;COCH; + H2O CH;C "OCH; + H,0 180 II C) CH;COCH3 + H¿®O D) equal amounts of A and B22- Give one example for the hydration of Alkene: That is the Addition of H2O byoxymercuration. Give the proper Mechanism if possible.23- Give one example for the hydration of Alkenes: that is: the addition of H2O byHydroboration.27) Give the products of the reaction and provide a step-by-step mechanism for the formation of the products. O not + H₂O HCI
- Predict the products, if any, of the following reactions. 20-35 (a) ascorbic ac (1) LiAlH4 -COOH (2) H3O+ (b) (1) NaCN CH₂Br (2) H3O+, heat (c) (1) SOCl2 (d) KMnO4, H₂O oct-4-yne (warm, concd.) (2) AlCl3 COOH (e) CH₂OH Na2Cr2O7, H2SO4 (f) Ph (1) BH3.THF CH3CH2-CH-COOH (2) H₁₂O+Provide the products and detailed arrow pushing mechanisms for the following reactions: OSIME3 EtN CO.Me 1. base, dilute solution (10mM) 2. NaOH/MEOH-H,0 Acid, heat CO.MeIdentify the major prouct of the folowing sololvsi reaction of 3bromo-1-methyiycopentene with methanol, Br CH,OH to
- 2. Show structures for the products formed in the following reactions. Indicate the major products where applicable. Br + NH₂ H HO OH Li(tBuQ)3AIH3 MeOH 1. LiAlH4 2. H₂O* 1. LiAlH4 2. H₂O* KMnO4 NaOH, A EtOH, NaBH CN cat. HCI14C labelled OTS RCO H 16. →product; Product of this reaction is : no label ОCOR OCOR (a) (b) (c) both (a) and (b) (d) None of these28. What is the major organic product of the following reaction? HO CI 1. (CH₂)₂Culi 2. H₂O A) I B) II C) III D) IV i c III ноха IV
- 13:27 ll 4G O. The following presented reaction scheme lead to the synthesis of which major product from benzene, assuming separation of products is possible? soj 1. NaOH Cl Product - Product H,SO, 2. H,0 FeCl OA Meta-Chlorophenol O B. para-ChloroSulfenic acid OC. Para-Chlorophenol OD. Meta-chloroaniline Add a caption... > Status (Custom)* Predict the products and stereochemistry for the following reduction reaction NaBH4 (a) EtOH H2 Lindlar catalyst (b) 3-Hexyne (c) 3-Hexyne (d) CEC H2 Ni₂B (P-2) Na NH3Write what the products A, B, C, D, E, F, G, H, I, J and K are in the reactions below. LIAIH, H2O CH;CH;CN H Eter