The melting point of water at the pressure of the interest (1 atm) is 0 °C and the enthalpy of fusion is 6 kJmol-. The boiling point 2. is 100 °C and the enthalpy of vaporization is 40kJmol-. Calculate AH and AS for the transformation of 5 grams of H20 (ice) from (s, -10/X °C) to H2O (g, 1000/X °C) cp (water)= 75.3 joule/mole.K. cp (ice)=36.2 joule/mole.K., cp H20(g) look at Appendix wwwww A

2. A 1 L, 100 g (dry weight) sample is removed from a continuous crystallizer which is operated with a residence time of 1000 s. The following particle size distribution is obtained for the sample: i) Size range (um) Mass (g) 200- 300- 400 500 600-700- 800- 300 400 500 600 700 800 900 0- 100- 100 200 2.5 26.0 30.0 21.0 12.0 6.0 2.0 0.5 0.0 Microscopy based on the sieve fractions has found that a volumetric shape correction factor, ky, of 0.52, for the crystal population and the crystal density has been found to be 2000 kg/m³ Determine whether the MSMPR model describes the system. If it does so, then determine the growth and nucleation rates for this system; if it does not, suggest why reasons that may cause deviation of this CSTR type crystallizer from the MSMPR model.

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