Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- A first order, liquid phase endothermic reaction A -> B + C, is conducted in a CSTR of 25 m3 volume operating at steady state. The feed concentration of A is 1.2 mol/L and enters the reactor at 8.7 L/s at 300 K. However, the reactor is heated in order to increase the rate and to achieve a conversion of 80%. a) Determine the temperature and heat transfer (kJ/s) requirement of the reactor needed to achieve this conversion. b) It is suggested to add a heat exchanger and a second reactor in series with the first CSTR. The coolant fluid enters and exits the reactor at a constant temperature which is less by 100 K from the exit temperature of the first reactor. Both reactors operate at the similar temperature. Calculate the conversion exiting the second reactor. Given that UA=2.3 kJ/s*K for which U is the overall heat transfer coefficient and A is the heat transfer area.arrow_forwardQuestion 1) The gas phase reaction (A→ B+C) must be carried out in a fixed-bed tubular reactor using a solid catalyst in a spherical shape of 0.4 cm in diameter. The reactor must operate isothermally at 573 K and an inlet pressure of 1 atm. The reaction is first order and the reactor is fed with pure A at a molar flow of FA0-1 g-mol/s. The internal diameter of the reactor must be 2.54 cm.It is known: -The reaction on the surface of the catalyst is of the type r₁=kCA.; -The particle density gp=2 g/cm3; -The porosity of the bed gl= 0.40.-This reaction, when carried out using the catalyst in powder form, obtained a speed of R 1 10-3 g-mol/g-cat.s, at a temperature of 573 K and pure reagent A at a pressure of 1 atm .-Consider that the reactor is being operated under conditions free from resistance to external mass transfer to the particle.-The effective molecular diffusivity in the gas phase (DAB) to solve this exercise must also be considered constant with the temperature and composition…arrow_forwardAn exothermic reaction, A ~ 2B, takes place adiabati-cally in a stirred-tank system. This liquid phase reaction occurs at constant volume in a 100-gal reactor. The reactioncan be considered to be first order and irreversible with therate constant given by k = 2.4 x 101se-20,000/T (min-1)where T is in oR. Using the information below, derive atransfer function relating the exit temperature T to the inletconcentration cAi· State any assumptions that you make.Simplify the transfer function by making a first-orderapproximation and show that the approximation is valid bycomparing the step responses of both the original and theapproximate models.Available Information(i) Nominal steady-state conditions are:T = 150 °F, CAi = 0.8lb mole/ft3q = 20 gaUmin = flow rate in and out of the reactor(ii) Physical property data for the mixture at the nominalsteady state: CP = 0.8 Btu!lb °F,p = 52lb/ft3, -t:lHR = 500 kJ/lb molearrow_forward
- QUESTION IN IMAGEEarrow_forwardProblem The following liquid-phase reaction is carried out in a CSTR with heat exchange: A + B The feed stream contains A and B in equimolar ratio. The total molar flow rate is 20 mol/s. The inlet temperature is 325 K, the inlet concentration of A is 1.5 molar, and the ambient temperature in the heat exchanger is 300 K. Calculate the reactor volume necessary to achieve 80% conversion. Additional information U= 80 J/m2 s K = 150 J/mol K Cpc E=25,000 J/mol k298 = 0.014 L/mol-s A=2 m? AHRxn(298) = -10,000 J/mol CPA= CPB= 100 J/mol K 20arrow_forwardA liquid reactant stream (1 mol/liter) passes through two mixed flow reactors in a series. The concentration of A in the exit of the first reactor is 0.5 mol/liter. Find the concentration in the exit stream of the second reactor. The reaction is second-order with respect to A and V2/V1 = 2. reactor designarrow_forward
- A liquid phase reaction A = R is carried out in a series of three completely mixed stirred tank reactors of equal size. The reaction rate constant k is 0.066/min. Overall conversion is 90%. The feed rate is 10 L/min. The feed contains only A in concentration of 1 mol/L. What is the average space time for each reactor?What is the concentration from the second reactor in mol/L?arrow_forwardThe liquid phase reaction A + B → C follows an elementary law of velocity and occurs isothermally in a flow-through system. The rules for the feed streams of A and B are 2.0 mol/L before mixing. The volumetric flow rate of each stream is 5 dm3/min, and the inlet temperature is 300 K. The streams are mixed just before entering. Two reactors are available. One is a 200 dm3 CSTR, which can be heated to 77oC or cooled to 0oC; another is an 800 dm3 PFR, operated at 300 K, which cannot be heated or cooled. Note that k = 0.07 dm3 / mol.min at 300K and E = 20 kcal / mol. (A) What conversion would be achieved if the CSTR and PFR were operated at 300K and connected in series? And in parallel with 5 mols/min each? (B)Knowing that the operating times (loading, unloading, heating, cleaning, etc.) of the batch reactor is around 3 h, what volume of batch reactor would be necessary to process, per day, the same amount of species A as in reactors with Flow so as to achieve 90% conversion?arrow_forwardFirst Orderarrow_forward
- The disinfection of water is carried out in a stirred tank. The treatment process has water as the input at a rate of 38 000 L/h. The tank carries 3800 L of water at all times. Sufficient chlorine is fed to the water. The rate of disinfection can be described as a first-order reaction with a rate constant of 0.055/min. The efficiency of the system can be expected to be (A) 0.050 (В) 0.25 (C) 0.50 (D) 0.75arrow_forwardProblem 4 The reversible, exothermic, liquid phase, homogeneous reaction A ₹R is being carried out in two ideal CSTRs. Both reactors operate at 150°C. The molar flow rate of A entering the first CSTR is 55,000 mol/h, the concentration of A in this stream is 6.5 mol/L, and the concentration of R is zero. The fractional conversion of A in the outlet stream from the second CSTR is 0.75. The fractional conversion is based on the molar flow rate entering the first CSTR. The reaction is first order in both directions. The rate constant for the forward reaction is 1.3 h-¹ and the equilibrium constant based on concentration at 150°C is 10.0. If the volume of the second CSTR is 10,000 L, what is the required volume of the first CSTR?arrow_forwardQUESTION IN IMAGEEarrow_forward
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